New complex dimensionless variable in cyclic staircase voltammetry on the rotating disk electrode

New complex dimensionless variable in cyclic staircase voltammetry on the rotating disk electrode

Cyclic staircase voltammograms of a simple, reversible oxidation on the rotating disk electrode is analysed by the digital simulation. It is demonstrated that the peak currents and potentials depend on the single dimensionless variable that considers nonlinear relationship between peak currents and...

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Main Author: Milivoj Lovrić
Format: Article
Language:English
Published: International Association of Physical Chemists (IAPC) 2021-09-01
Series:Journal of Electrochemical Science and Engineering
Subjects:
digital simulation
sigmoidal dependence
reversible oxidation
Online Access:http://pub.iapchem.org/ojs/index.php/JESE/article/view/1069
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spelling doaj-8e9facc409994fe3869eaa5c702da9992021-09-10T07:48:12ZengInternational Association of Physical Chemists (IAPC)Journal of Electrochemical Science and Engineering1847-92862021-09-0111310.5599/jese.1069New complex dimensionless variable in cyclic staircase voltammetry on the rotating disk electrodeMilivoj Lovrić0Divkovićeva 13, Zagreb 10090, Croatia Cyclic staircase voltammograms of a simple, reversible oxidation on the rotating disk electrode is analysed by the digital simulation. It is demonstrated that the peak currents and potentials depend on the single dimensionless variable that considers nonlinear relationship between peak currents and the potential increment. The reverse, cathodic branch of voltammograms depends on this variable differently than the anodic one. http://pub.iapchem.org/ojs/index.php/JESE/article/view/1069digital simulationsigmoidal dependencereversible oxidation
collection DOAJ
language English
format Article
sources DOAJ
author Milivoj Lovrić
spellingShingle Milivoj Lovrić
New complex dimensionless variable in cyclic staircase voltammetry on the rotating disk electrode
Journal of Electrochemical Science and Engineering
digital simulation
sigmoidal dependence
reversible oxidation
author_facet Milivoj Lovrić
author_sort Milivoj Lovrić
title New complex dimensionless variable in cyclic staircase voltammetry on the rotating disk electrode
title_short New complex dimensionless variable in cyclic staircase voltammetry on the rotating disk electrode
title_full New complex dimensionless variable in cyclic staircase voltammetry on the rotating disk electrode
title_fullStr New complex dimensionless variable in cyclic staircase voltammetry on the rotating disk electrode
title_full_unstemmed New complex dimensionless variable in cyclic staircase voltammetry on the rotating disk electrode
title_sort new complex dimensionless variable in cyclic staircase voltammetry on the rotating disk electrode
publisher International Association of Physical Chemists (IAPC)
series Journal of Electrochemical Science and Engineering
issn 1847-9286
publishDate 2021-09-01
description Cyclic staircase voltammograms of a simple, reversible oxidation on the rotating disk electrode is analysed by the digital simulation. It is demonstrated that the peak currents and potentials depend on the single dimensionless variable that considers nonlinear relationship between peak currents and the potential increment. The reverse, cathodic branch of voltammograms depends on this variable differently than the anodic one.
topic digital simulation
sigmoidal dependence
reversible oxidation
url http://pub.iapchem.org/ojs/index.php/JESE/article/view/1069
work_keys_str_mv AT milivojlovric newcomplexdimensionlessvariableincyclicstaircasevoltammetryontherotatingdiskelectrode
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