Poly[diethylenetriammonium [aquadi-μ2-sulfato-sulfatocerium(III)]]

Poly[diethylenetriammonium [aquadi-μ2-sulfato-sulfatocerium(III)]]

A new organically templated open-framework cerium sulfate, {(C4H16N3)[Ce(SO4)3(H2O)]}n, was hydrothermally synthesized. The CeIII cation is nine-coordinated by nine O atoms, including one water molecule. Two of the SO4 groups afford one monodentate and bidentate linkages as the bridge to connect adj...

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Main Authors: Xiu-Mei Zhang, Ya-Feng Li
Format: Article
Language:English
Published: International Union of Crystallography 2010-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810016600
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spelling doaj-8e7116b8750f471987ec634dcd8fca3d2020-11-24T23:55:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666m649m65010.1107/S1600536810016600Poly[diethylenetriammonium [aquadi-μ2-sulfato-sulfatocerium(III)]]Xiu-Mei ZhangYa-Feng LiA new organically templated open-framework cerium sulfate, {(C4H16N3)[Ce(SO4)3(H2O)]}n, was hydrothermally synthesized. The CeIII cation is nine-coordinated by nine O atoms, including one water molecule. Two of the SO4 groups afford one monodentate and bidentate linkages as the bridge to connect adjacent CeIII cations, while the third SO4 group attaches the CeIII cation in a bidentate mode. The crystal structure consists of layers composed of eight-membered-ring networks formed by four CeO9 polyhedra and four SO4 tetrahedra. The triply protonated diethylenetriamine cations are located between adjacent layers and connect the layers via hydrogen bonds. http://scripts.iucr.org/cgi-bin/paper?S1600536810016600
collection DOAJ
language English
format Article
sources DOAJ
author Xiu-Mei Zhang
Ya-Feng Li
spellingShingle Xiu-Mei Zhang
Ya-Feng Li
Poly[diethylenetriammonium [aquadi-μ2-sulfato-sulfatocerium(III)]]
Acta Crystallographica Section E
author_facet Xiu-Mei Zhang
Ya-Feng Li
author_sort Xiu-Mei Zhang
title Poly[diethylenetriammonium [aquadi-μ2-sulfato-sulfatocerium(III)]]
title_short Poly[diethylenetriammonium [aquadi-μ2-sulfato-sulfatocerium(III)]]
title_full Poly[diethylenetriammonium [aquadi-μ2-sulfato-sulfatocerium(III)]]
title_fullStr Poly[diethylenetriammonium [aquadi-μ2-sulfato-sulfatocerium(III)]]
title_full_unstemmed Poly[diethylenetriammonium [aquadi-μ2-sulfato-sulfatocerium(III)]]
title_sort poly[diethylenetriammonium [aquadi-μ2-sulfato-sulfatocerium(iii)]]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-06-01
description A new organically templated open-framework cerium sulfate, {(C4H16N3)[Ce(SO4)3(H2O)]}n, was hydrothermally synthesized. The CeIII cation is nine-coordinated by nine O atoms, including one water molecule. Two of the SO4 groups afford one monodentate and bidentate linkages as the bridge to connect adjacent CeIII cations, while the third SO4 group attaches the CeIII cation in a bidentate mode. The crystal structure consists of layers composed of eight-membered-ring networks formed by four CeO9 polyhedra and four SO4 tetrahedra. The triply protonated diethylenetriamine cations are located between adjacent layers and connect the layers via hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810016600
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AT yafengli polydiethylenetriammoniumaquadiamp9562sulfatosulfatoceriumiii
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