Effects of Surface Heterogeneity in Adsorption from Binary Solutions on Modified Silica Gels

The adsorption of benzene from cyclohexane solutions on modified silica gels is analysed using expressions derived from the model of adsorption of binary solutions on heterogeneous solid surfaces. The adsorption equation is found to represent the data for several systems and leads to a method for es...

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Main Author: J. Goworek
Format: Article
Language:English
Published: Hindawi - SAGE Publishing 1987-12-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/026361748700400402
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spelling doaj-8dd95d3616c44b668740d273ab8751142021-04-02T09:20:01ZengHindawi - SAGE PublishingAdsorption Science & Technology0263-61742048-40381987-12-01410.1177/026361748700400402Effects of Surface Heterogeneity in Adsorption from Binary Solutions on Modified Silica GelsJ. GoworekThe adsorption of benzene from cyclohexane solutions on modified silica gels is analysed using expressions derived from the model of adsorption of binary solutions on heterogeneous solid surfaces. The adsorption equation is found to represent the data for several systems and leads to a method for estimating the energetical heterogeneity of the adsorbent surface. The energy distribution functions for investigated systems are calculated. The same adsorption data are analysed using the simple form of isotherm equation for adsorption of binary liquid mixtures on heterogeneous solid surfaces. The results obtained by using two different methods for the same adsorption systems are discussed.https://doi.org/10.1177/026361748700400402
collection DOAJ
language English
format Article
sources DOAJ
author J. Goworek
spellingShingle J. Goworek
Effects of Surface Heterogeneity in Adsorption from Binary Solutions on Modified Silica Gels
Adsorption Science & Technology
author_facet J. Goworek
author_sort J. Goworek
title Effects of Surface Heterogeneity in Adsorption from Binary Solutions on Modified Silica Gels
title_short Effects of Surface Heterogeneity in Adsorption from Binary Solutions on Modified Silica Gels
title_full Effects of Surface Heterogeneity in Adsorption from Binary Solutions on Modified Silica Gels
title_fullStr Effects of Surface Heterogeneity in Adsorption from Binary Solutions on Modified Silica Gels
title_full_unstemmed Effects of Surface Heterogeneity in Adsorption from Binary Solutions on Modified Silica Gels
title_sort effects of surface heterogeneity in adsorption from binary solutions on modified silica gels
publisher Hindawi - SAGE Publishing
series Adsorption Science & Technology
issn 0263-6174
2048-4038
publishDate 1987-12-01
description The adsorption of benzene from cyclohexane solutions on modified silica gels is analysed using expressions derived from the model of adsorption of binary solutions on heterogeneous solid surfaces. The adsorption equation is found to represent the data for several systems and leads to a method for estimating the energetical heterogeneity of the adsorbent surface. The energy distribution functions for investigated systems are calculated. The same adsorption data are analysed using the simple form of isotherm equation for adsorption of binary liquid mixtures on heterogeneous solid surfaces. The results obtained by using two different methods for the same adsorption systems are discussed.
url https://doi.org/10.1177/026361748700400402
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