N,N′-Di-tert-butyl-N′′-(2-chloroacetyl)phosphoric triamide
The P atom in the title molecule, C10H23ClN3O2P, has a distorted tetrahedral coordination. In the C(O)NHP(O) unit, which has syn-oriented phosphoryl and N—H groups, the P—N bond of 1.703 (2) Å is longer and the O—P&am...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811040773 |
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doaj-8d659adedeb54424b5eed70e8f3c0e292020-11-24T21:30:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-11-016711o2848o284810.1107/S1600536811040773N,N′-Di-tert-butyl-N′′-(2-chloroacetyl)phosphoric triamideMehrdad PourayoubiBehrouz ElahiMasood ParvezThe P atom in the title molecule, C10H23ClN3O2P, has a distorted tetrahedral coordination. In the C(O)NHP(O) unit, which has syn-oriented phosphoryl and N—H groups, the P—N bond of 1.703 (2) Å is longer and the O—P—N angle of 103.86 (7)° is contracted compared with the respective values in the two P(O)NHC(CH3)3 units [P—N = 1.632 (2) and 1.624 (2) Å; O—P—N = 116.80 (8) and 115.32 (8)°]. In the crystal, each molecule is hydrogen bonded to two adjacent molecules via N—H...O hydrogen bonds, forming a linear sequence of alternating R22(8) and R22(12)/R21(6)-fused rings along [010]. The O atom of the carbonyl group acts as a double H-atom acceptor.http://scripts.iucr.org/cgi-bin/paper?S1600536811040773 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Mehrdad Pourayoubi Behrouz Elahi Masood Parvez |
| spellingShingle |
Mehrdad Pourayoubi Behrouz Elahi Masood Parvez N,N′-Di-tert-butyl-N′′-(2-chloroacetyl)phosphoric triamide Acta Crystallographica Section E |
| author_facet |
Mehrdad Pourayoubi Behrouz Elahi Masood Parvez |
| author_sort |
Mehrdad Pourayoubi |
| title |
N,N′-Di-tert-butyl-N′′-(2-chloroacetyl)phosphoric triamide |
| title_short |
N,N′-Di-tert-butyl-N′′-(2-chloroacetyl)phosphoric triamide |
| title_full |
N,N′-Di-tert-butyl-N′′-(2-chloroacetyl)phosphoric triamide |
| title_fullStr |
N,N′-Di-tert-butyl-N′′-(2-chloroacetyl)phosphoric triamide |
| title_full_unstemmed |
N,N′-Di-tert-butyl-N′′-(2-chloroacetyl)phosphoric triamide |
| title_sort |
n,n′-di-tert-butyl-n′′-(2-chloroacetyl)phosphoric triamide |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2011-11-01 |
| description |
The P atom in the title molecule, C10H23ClN3O2P, has a distorted tetrahedral coordination. In the C(O)NHP(O) unit, which has syn-oriented phosphoryl and N—H groups, the P—N bond of 1.703 (2) Å is longer and the O—P—N angle of 103.86 (7)° is contracted compared with the respective values in the two P(O)NHC(CH3)3 units [P—N = 1.632 (2) and 1.624 (2) Å; O—P—N = 116.80 (8) and 115.32 (8)°]. In the crystal, each molecule is hydrogen bonded to two adjacent molecules via N—H...O hydrogen bonds, forming a linear sequence of alternating R22(8) and R22(12)/R21(6)-fused rings along [010]. The O atom of the carbonyl group acts as a double H-atom acceptor. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811040773 |
| work_keys_str_mv |
AT mehrdadpourayoubi nnamp8242ditertbutylnamp8242amp82422chloroacetylphosphorictriamide AT behrouzelahi nnamp8242ditertbutylnamp8242amp82422chloroacetylphosphorictriamide AT masoodparvez nnamp8242ditertbutylnamp8242amp82422chloroacetylphosphorictriamide |
| _version_ |
1725961591252320256 |