Bis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3N,N′,O]cobalt(II) dihydrate

Bis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3N,N′,O]cobalt(II) dihydrate

The title complex, [Co(C12H9N2O3S)2]·2H2O, has site symmetry 2 with the CoII cation located on a twofold rotation axis. Two tridentate 2-(2-pyridylmethyleneamino)benzenesulfonate (paba) ligands chelate to the CoII cation in a distorted octahedral geometry. The pyridine and benzene rings...

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Main Authors: Xue-Ren Huang, Miao Ou-Yang, Ge-Ge Yang, Xiu-Jin Meng, Yi-Min Jiang
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809043918
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spelling doaj-8d54d0215eb646f4931cfdef6c0512002020-11-24T21:26:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1465m146510.1107/S1600536809043918Bis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3N,N′,O]cobalt(II) dihydrateXue-Ren HuangMiao Ou-YangGe-Ge YangXiu-Jin MengYi-Min JiangThe title complex, [Co(C12H9N2O3S)2]·2H2O, has site symmetry 2 with the CoII cation located on a twofold rotation axis. Two tridentate 2-(2-pyridylmethyleneamino)benzenesulfonate (paba) ligands chelate to the CoII cation in a distorted octahedral geometry. The pyridine and benzene rings in the paba ligand are oriented at a dihedral angle of 42.86 (13)°. Intermolecular O—H...O and C—H...O hydrogen bonding is present in the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536809043918
collection DOAJ
language English
format Article
sources DOAJ
author Xue-Ren Huang
Miao Ou-Yang
Ge-Ge Yang
Xiu-Jin Meng
Yi-Min Jiang
spellingShingle Xue-Ren Huang
Miao Ou-Yang
Ge-Ge Yang
Xiu-Jin Meng
Yi-Min Jiang
Bis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3N,N′,O]cobalt(II) dihydrate
Acta Crystallographica Section E
author_facet Xue-Ren Huang
Miao Ou-Yang
Ge-Ge Yang
Xiu-Jin Meng
Yi-Min Jiang
author_sort Xue-Ren Huang
title Bis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3N,N′,O]cobalt(II) dihydrate
title_short Bis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3N,N′,O]cobalt(II) dihydrate
title_full Bis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3N,N′,O]cobalt(II) dihydrate
title_fullStr Bis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3N,N′,O]cobalt(II) dihydrate
title_full_unstemmed Bis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3N,N′,O]cobalt(II) dihydrate
title_sort bis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3n,n′,o]cobalt(ii) dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-11-01
description The title complex, [Co(C12H9N2O3S)2]·2H2O, has site symmetry 2 with the CoII cation located on a twofold rotation axis. Two tridentate 2-(2-pyridylmethyleneamino)benzenesulfonate (paba) ligands chelate to the CoII cation in a distorted octahedral geometry. The pyridine and benzene rings in the paba ligand are oriented at a dihedral angle of 42.86 (13)°. Intermolecular O—H...O and C—H...O hydrogen bonding is present in the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809043918
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AT miaoouyang bis22pyridylmethyleneaminobenzenesulfonatoamp9543nnamp8242ocobaltiidihydrate
AT gegeyang bis22pyridylmethyleneaminobenzenesulfonatoamp9543nnamp8242ocobaltiidihydrate
AT xiujinmeng bis22pyridylmethyleneaminobenzenesulfonatoamp9543nnamp8242ocobaltiidihydrate
AT yiminjiang bis22pyridylmethyleneaminobenzenesulfonatoamp9543nnamp8242ocobaltiidihydrate
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