Bis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3N,N′,O]cobalt(II) dihydrate

Bis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3N,N′,O]cobalt(II) dihydrate

The title complex, [Co(C12H9N2O3S)2]·2H2O, has site symmetry 2 with the CoII cation located on a twofold rotation axis. Two tridentate 2-(2-pyridylmethyleneamino)benzenesulfonate (paba) ligands chelate to the CoII cation in a distorted octahedral geometry. The pyridine and benzene rings...

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Bibliographic Details
Main Authors: Xue-Ren Huang, Miao Ou-Yang, Ge-Ge Yang, Xiu-Jin Meng, Yi-Min Jiang
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809043918
Description
Summary:The title complex, [Co(C12H9N2O3S)2]·2H2O, has site symmetry 2 with the CoII cation located on a twofold rotation axis. Two tridentate 2-(2-pyridylmethyleneamino)benzenesulfonate (paba) ligands chelate to the CoII cation in a distorted octahedral geometry. The pyridine and benzene rings in the paba ligand are oriented at a dihedral angle of 42.86 (13)°. Intermolecular O—H...O and C—H...O hydrogen bonding is present in the crystal structure.
ISSN:1600-5368

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