Preparation and properties of novel flame-retardant PBS wood-plastic composites

Poly (butylene succinate) (PBS), as a fully biodegradable thermoplastic, have developed rapidly due to its integrated performance and processibility. The CaCO3 as a reinforcing component, and AHP, APP and CaHP as a flame-retardant component were separately incorporated into PBS matrix. A series of P...

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Main Authors: ShuaiCheng Jiang, YaFeng Yang, ShengBo Ge, ZhongFeng Zhang, WanXi Peng
Format: Article
Language:English
Published: Elsevier 2018-09-01
Series:Arabian Journal of Chemistry
Online Access:http://www.sciencedirect.com/science/article/pii/S1878535217302666
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spelling doaj-8d114bb516df4623a3335f401ce395402020-11-25T01:06:33ZengElsevierArabian Journal of Chemistry1878-53522018-09-01116844857Preparation and properties of novel flame-retardant PBS wood-plastic compositesShuaiCheng Jiang0YaFeng Yang1ShengBo Ge2ZhongFeng Zhang3WanXi Peng4School of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, ChinaSchool of Forestry, Henan Agricultural University, Zhengzhou 450002, ChinaSchool of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, ChinaSchool of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China; Corresponding authors at: School of Forestry, Henan Agricultural University, Zhengzhou 450002, China (W. Peng).School of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China; School of Forestry, Henan Agricultural University, Zhengzhou 450002, China; Corresponding authors at: School of Forestry, Henan Agricultural University, Zhengzhou 450002, China (W. Peng).Poly (butylene succinate) (PBS), as a fully biodegradable thermoplastic, have developed rapidly due to its integrated performance and processibility. The CaCO3 as a reinforcing component, and AHP, APP and CaHP as a flame-retardant component were separately incorporated into PBS matrix. A series of PBS-based composites were fabricated via melting blending using internal mixer followed by injection molding. The results show that the different filling ratio has a certain influence on the mechanical properties of the composites. When the filling amount of wood powder is 40 copies, the composite mechanical properties of the composite is better. CaCO3 addition, the composite material of the bending strength, tensile strength have improved significantly. The results showed that small amount of AHP, APP and CaHP improved the tensile strength of PBS composites, however, the tensile strength decreased as further increase amount of AHP, APP and CaHP. Cone Calorimeter testing revealed that, the combination of AHP, APP and CaHP could significantly reduce the pHRR and the total heart release (THR) of the composites. TGA test indicated that the addition of AHP, APP and CaHP could significantly increase the char residue and reduce the mass loss rate. TGA test indicated that the addition of AHP, APP and CaHP could significantly increase the char residue and reduce the mass loss rate. Through the research of mechanical and thermal properties of PBS composite, it could lay a foundation of the application of PBS composite in different fields. Keywords: Poly (butylene succinate), Crystallization behavior, Flame retardant, AHP, APP, CaHPhttp://www.sciencedirect.com/science/article/pii/S1878535217302666
collection DOAJ
language English
format Article
sources DOAJ
author ShuaiCheng Jiang
YaFeng Yang
ShengBo Ge
ZhongFeng Zhang
WanXi Peng
spellingShingle ShuaiCheng Jiang
YaFeng Yang
ShengBo Ge
ZhongFeng Zhang
WanXi Peng
Preparation and properties of novel flame-retardant PBS wood-plastic composites
Arabian Journal of Chemistry
author_facet ShuaiCheng Jiang
YaFeng Yang
ShengBo Ge
ZhongFeng Zhang
WanXi Peng
author_sort ShuaiCheng Jiang
title Preparation and properties of novel flame-retardant PBS wood-plastic composites
title_short Preparation and properties of novel flame-retardant PBS wood-plastic composites
title_full Preparation and properties of novel flame-retardant PBS wood-plastic composites
title_fullStr Preparation and properties of novel flame-retardant PBS wood-plastic composites
title_full_unstemmed Preparation and properties of novel flame-retardant PBS wood-plastic composites
title_sort preparation and properties of novel flame-retardant pbs wood-plastic composites
publisher Elsevier
series Arabian Journal of Chemistry
issn 1878-5352
publishDate 2018-09-01
description Poly (butylene succinate) (PBS), as a fully biodegradable thermoplastic, have developed rapidly due to its integrated performance and processibility. The CaCO3 as a reinforcing component, and AHP, APP and CaHP as a flame-retardant component were separately incorporated into PBS matrix. A series of PBS-based composites were fabricated via melting blending using internal mixer followed by injection molding. The results show that the different filling ratio has a certain influence on the mechanical properties of the composites. When the filling amount of wood powder is 40 copies, the composite mechanical properties of the composite is better. CaCO3 addition, the composite material of the bending strength, tensile strength have improved significantly. The results showed that small amount of AHP, APP and CaHP improved the tensile strength of PBS composites, however, the tensile strength decreased as further increase amount of AHP, APP and CaHP. Cone Calorimeter testing revealed that, the combination of AHP, APP and CaHP could significantly reduce the pHRR and the total heart release (THR) of the composites. TGA test indicated that the addition of AHP, APP and CaHP could significantly increase the char residue and reduce the mass loss rate. TGA test indicated that the addition of AHP, APP and CaHP could significantly increase the char residue and reduce the mass loss rate. Through the research of mechanical and thermal properties of PBS composite, it could lay a foundation of the application of PBS composite in different fields. Keywords: Poly (butylene succinate), Crystallization behavior, Flame retardant, AHP, APP, CaHP
url http://www.sciencedirect.com/science/article/pii/S1878535217302666
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