Preparation and properties of novel flame-retardant PBS wood-plastic composites
Poly (butylene succinate) (PBS), as a fully biodegradable thermoplastic, have developed rapidly due to its integrated performance and processibility. The CaCO3 as a reinforcing component, and AHP, APP and CaHP as a flame-retardant component were separately incorporated into PBS matrix. A series of P...
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doaj-8d114bb516df4623a3335f401ce395402020-11-25T01:06:33ZengElsevierArabian Journal of Chemistry1878-53522018-09-01116844857Preparation and properties of novel flame-retardant PBS wood-plastic compositesShuaiCheng Jiang0YaFeng Yang1ShengBo Ge2ZhongFeng Zhang3WanXi Peng4School of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, ChinaSchool of Forestry, Henan Agricultural University, Zhengzhou 450002, ChinaSchool of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, ChinaSchool of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China; Corresponding authors at: School of Forestry, Henan Agricultural University, Zhengzhou 450002, China (W. Peng).School of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China; School of Forestry, Henan Agricultural University, Zhengzhou 450002, China; Corresponding authors at: School of Forestry, Henan Agricultural University, Zhengzhou 450002, China (W. Peng).Poly (butylene succinate) (PBS), as a fully biodegradable thermoplastic, have developed rapidly due to its integrated performance and processibility. The CaCO3 as a reinforcing component, and AHP, APP and CaHP as a flame-retardant component were separately incorporated into PBS matrix. A series of PBS-based composites were fabricated via melting blending using internal mixer followed by injection molding. The results show that the different filling ratio has a certain influence on the mechanical properties of the composites. When the filling amount of wood powder is 40 copies, the composite mechanical properties of the composite is better. CaCO3 addition, the composite material of the bending strength, tensile strength have improved significantly. The results showed that small amount of AHP, APP and CaHP improved the tensile strength of PBS composites, however, the tensile strength decreased as further increase amount of AHP, APP and CaHP. Cone Calorimeter testing revealed that, the combination of AHP, APP and CaHP could significantly reduce the pHRR and the total heart release (THR) of the composites. TGA test indicated that the addition of AHP, APP and CaHP could significantly increase the char residue and reduce the mass loss rate. TGA test indicated that the addition of AHP, APP and CaHP could significantly increase the char residue and reduce the mass loss rate. Through the research of mechanical and thermal properties of PBS composite, it could lay a foundation of the application of PBS composite in different fields. Keywords: Poly (butylene succinate), Crystallization behavior, Flame retardant, AHP, APP, CaHPhttp://www.sciencedirect.com/science/article/pii/S1878535217302666 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
ShuaiCheng Jiang YaFeng Yang ShengBo Ge ZhongFeng Zhang WanXi Peng |
spellingShingle |
ShuaiCheng Jiang YaFeng Yang ShengBo Ge ZhongFeng Zhang WanXi Peng Preparation and properties of novel flame-retardant PBS wood-plastic composites Arabian Journal of Chemistry |
author_facet |
ShuaiCheng Jiang YaFeng Yang ShengBo Ge ZhongFeng Zhang WanXi Peng |
author_sort |
ShuaiCheng Jiang |
title |
Preparation and properties of novel flame-retardant PBS wood-plastic composites |
title_short |
Preparation and properties of novel flame-retardant PBS wood-plastic composites |
title_full |
Preparation and properties of novel flame-retardant PBS wood-plastic composites |
title_fullStr |
Preparation and properties of novel flame-retardant PBS wood-plastic composites |
title_full_unstemmed |
Preparation and properties of novel flame-retardant PBS wood-plastic composites |
title_sort |
preparation and properties of novel flame-retardant pbs wood-plastic composites |
publisher |
Elsevier |
series |
Arabian Journal of Chemistry |
issn |
1878-5352 |
publishDate |
2018-09-01 |
description |
Poly (butylene succinate) (PBS), as a fully biodegradable thermoplastic, have developed rapidly due to its integrated performance and processibility. The CaCO3 as a reinforcing component, and AHP, APP and CaHP as a flame-retardant component were separately incorporated into PBS matrix. A series of PBS-based composites were fabricated via melting blending using internal mixer followed by injection molding. The results show that the different filling ratio has a certain influence on the mechanical properties of the composites. When the filling amount of wood powder is 40 copies, the composite mechanical properties of the composite is better. CaCO3 addition, the composite material of the bending strength, tensile strength have improved significantly. The results showed that small amount of AHP, APP and CaHP improved the tensile strength of PBS composites, however, the tensile strength decreased as further increase amount of AHP, APP and CaHP. Cone Calorimeter testing revealed that, the combination of AHP, APP and CaHP could significantly reduce the pHRR and the total heart release (THR) of the composites. TGA test indicated that the addition of AHP, APP and CaHP could significantly increase the char residue and reduce the mass loss rate. TGA test indicated that the addition of AHP, APP and CaHP could significantly increase the char residue and reduce the mass loss rate. Through the research of mechanical and thermal properties of PBS composite, it could lay a foundation of the application of PBS composite in different fields. Keywords: Poly (butylene succinate), Crystallization behavior, Flame retardant, AHP, APP, CaHP |
url |
http://www.sciencedirect.com/science/article/pii/S1878535217302666 |
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