Bis-Phenoxo-Cu<sup>II</sup><sub>2</sub> Complexes: Formal Aromatic Hydroxylation via Aryl-Cu<sup>III</sup> Intermediate Species

Bis-Phenoxo-Cu<sup>II</sup><sub>2</sub> Complexes: Formal Aromatic Hydroxylation via Aryl-Cu<sup>III</sup> Intermediate Species

Ullmann-type copper-mediated arylC-O bond formation has attracted the attention of the catalysis and organometallic communities, although the mechanism of these copper-catalyzed coupling reactions remains a subject of debate. We have designed well-defined triazamacrocyclic-based aryl-Cu<sup>II...

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Bibliographic Details
Main Authors: Xavi Ribas, Raül Xifra, Xavier Fontrodona
Format: Article
Language:English
Published: MDPI AG 2020-10-01
Series:Molecules
Subjects:
organometallic Cu<sup>III</sup>
C-O cross coupling
phenol synthesis
phenoxo-bridged Cu<sup>II</sup> complexes
aromatic hydroxylation
copper
Online Access:https://www.mdpi.com/1420-3049/25/20/4595

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