Tetracarbonylbis(η5-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvate

Tetracarbonylbis(η5-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvate

The asymmetric unit of the title compound, [Mo2(η5-C5H5)2(C22H29P)2(CO)4]·2C4H8O, contains two half-molecules of the organometallic species and two solvent molecules. Both organometallic molecules are completed by crystallographic inversion symmetry, yielding dimeric units...

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Main Authors: David R Tyler, Lev N. Zakharov, Ginger Shultz
Format: Article
Language:English
Published: International Union of Crystallography 2009-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809046327
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spelling doaj-8cc48fb6748448dba8879de55aeb3e5c2020-11-24T20:48:53ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1545m154510.1107/S1600536809046327Tetracarbonylbis(η5-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvateDavid R TylerLev N. ZakharovGinger ShultzThe asymmetric unit of the title compound, [Mo2(η5-C5H5)2(C22H29P)2(CO)4]·2C4H8O, contains two half-molecules of the organometallic species and two solvent molecules. Both organometallic molecules are completed by crystallographic inversion symmetry, yielding dimeric units with Mo—Mo single-bond lengths of 3.2703 (6) and 3.2548 (6) Å. Each Mo atom is also coordinated by an η5-cyclopentdienyl ligand, two carbonyl ligands, and a (dec-9-en-1-yl)diphenylphosphine ligand. http://scripts.iucr.org/cgi-bin/paper?S1600536809046327
collection DOAJ
language English
format Article
sources DOAJ
author David R Tyler
Lev N. Zakharov
Ginger Shultz
spellingShingle David R Tyler
Lev N. Zakharov
Ginger Shultz
Tetracarbonylbis(η5-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvate
Acta Crystallographica Section E
author_facet David R Tyler
Lev N. Zakharov
Ginger Shultz
author_sort David R Tyler
title Tetracarbonylbis(η5-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvate
title_short Tetracarbonylbis(η5-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvate
title_full Tetracarbonylbis(η5-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvate
title_fullStr Tetracarbonylbis(η5-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvate
title_full_unstemmed Tetracarbonylbis(η5-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvate
title_sort tetracarbonylbis(η5-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(mo—mo) tetrahydrofuran disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-12-01
description The asymmetric unit of the title compound, [Mo2(η5-C5H5)2(C22H29P)2(CO)4]·2C4H8O, contains two half-molecules of the organometallic species and two solvent molecules. Both organometallic molecules are completed by crystallographic inversion symmetry, yielding dimeric units with Mo—Mo single-bond lengths of 3.2703 (6) and 3.2548 (6) Å. Each Mo atom is also coordinated by an η5-cyclopentdienyl ligand, two carbonyl ligands, and a (dec-9-en-1-yl)diphenylphosphine ligand.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809046327
work_keys_str_mv AT davidrtyler tetracarbonylbisamp9515cyclopentadienylbisdec9en1yldiphenylphosphinedimolybdenum0moamp8212motetrahydrofurandisolvate
AT levnzakharov tetracarbonylbisamp9515cyclopentadienylbisdec9en1yldiphenylphosphinedimolybdenum0moamp8212motetrahydrofurandisolvate
AT gingershultz tetracarbonylbisamp9515cyclopentadienylbisdec9en1yldiphenylphosphinedimolybdenum0moamp8212motetrahydrofurandisolvate
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