Synthesis new substances of norbornene`s series toward photochemical energy storage
Modification of norbornadien (NBD) for using as solar energy storage was attempted. Synthesed adducts was investigated in the reaction of catalytic allylation by Pd<sub>3</sub>(OAc)<sub>6</sub> – PPh<sub>3</sub> and...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | Russian |
| Published: |
MIREA - Russian Technological University
2007-04-01
|
| Series: | Тонкие химические технологии |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/1309 |
| Summary: | Modification of norbornadien (NBD) for using as solar energy storage was attempted. Synthesed adducts was investigated in the reaction of catalytic allylation by Pd<sub>3</sub>(OAc)<sub>6</sub> – PPh<sub>3</sub> and Ni(C<sub>3</sub>H<sub>5</sub>)<sub>2</sub> – P(i-C<sub>3</sub>H<sub>7</sub>O)<sub>3</sub> complexes and reaction parametres were optimized. Supramolecular substances, combinated NBD and 4-oxoretinal or 5,6-dioxo-5,6-sekoretinal, were suggested toward photochemical energy storage and optical memory systems by means of the photochromic valence isomerization of the NBD – quadricyclane system. |
|---|---|
| ISSN: | 2410-6593 2686-7575 |