Frontal Analysis Continuous Capillary Electrophoresis Study on the Interaction of an Amphiphilic Alternating Copolymer with Triton X-100

The interaction of amphiphilic alternating copolymers of sodium maleate and dodecyl vinyl ether (Mal/C12) with a nonionic surfactant, Triton X-100 (TX), was investigated by frontal analysis continuous capillary electrophoresis (FACCE). The binding isotherms obtained from FACCE data were indicative...

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Main Authors: Akihito Hashidzume, Takuya Shimomachi, Takahiro Sato
Format: Article
Language:English
Published: Hindawi Limited 2011-01-01
Series:International Journal of Analytical Chemistry
Online Access:http://dx.doi.org/10.1155/2011/617981
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spelling doaj-8c6db8e96df24ce29bb9401fb5581c7f2020-11-24T22:17:04ZengHindawi LimitedInternational Journal of Analytical Chemistry1687-87601687-87792011-01-01201110.1155/2011/617981617981Frontal Analysis Continuous Capillary Electrophoresis Study on the Interaction of an Amphiphilic Alternating Copolymer with Triton X-100Akihito Hashidzume0Takuya Shimomachi1Takahiro Sato2Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, JapanDepartment of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, JapanDepartment of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, JapanThe interaction of amphiphilic alternating copolymers of sodium maleate and dodecyl vinyl ether (Mal/C12) with a nonionic surfactant, Triton X-100 (TX), was investigated by frontal analysis continuous capillary electrophoresis (FACCE). The binding isotherms obtained from FACCE data were indicative of weak cooperative interaction for all the polymers examined. The cooperative interaction was also analyzed by the Hill model, and the results were compared with the previous results on the interaction of statistical copolymers of sodium 2-acrylamido-2-methylpropanesulfonate and N-dodecylmethacrylamide with TX.http://dx.doi.org/10.1155/2011/617981
collection DOAJ
language English
format Article
sources DOAJ
author Akihito Hashidzume
Takuya Shimomachi
Takahiro Sato
spellingShingle Akihito Hashidzume
Takuya Shimomachi
Takahiro Sato
Frontal Analysis Continuous Capillary Electrophoresis Study on the Interaction of an Amphiphilic Alternating Copolymer with Triton X-100
International Journal of Analytical Chemistry
author_facet Akihito Hashidzume
Takuya Shimomachi
Takahiro Sato
author_sort Akihito Hashidzume
title Frontal Analysis Continuous Capillary Electrophoresis Study on the Interaction of an Amphiphilic Alternating Copolymer with Triton X-100
title_short Frontal Analysis Continuous Capillary Electrophoresis Study on the Interaction of an Amphiphilic Alternating Copolymer with Triton X-100
title_full Frontal Analysis Continuous Capillary Electrophoresis Study on the Interaction of an Amphiphilic Alternating Copolymer with Triton X-100
title_fullStr Frontal Analysis Continuous Capillary Electrophoresis Study on the Interaction of an Amphiphilic Alternating Copolymer with Triton X-100
title_full_unstemmed Frontal Analysis Continuous Capillary Electrophoresis Study on the Interaction of an Amphiphilic Alternating Copolymer with Triton X-100
title_sort frontal analysis continuous capillary electrophoresis study on the interaction of an amphiphilic alternating copolymer with triton x-100
publisher Hindawi Limited
series International Journal of Analytical Chemistry
issn 1687-8760
1687-8779
publishDate 2011-01-01
description The interaction of amphiphilic alternating copolymers of sodium maleate and dodecyl vinyl ether (Mal/C12) with a nonionic surfactant, Triton X-100 (TX), was investigated by frontal analysis continuous capillary electrophoresis (FACCE). The binding isotherms obtained from FACCE data were indicative of weak cooperative interaction for all the polymers examined. The cooperative interaction was also analyzed by the Hill model, and the results were compared with the previous results on the interaction of statistical copolymers of sodium 2-acrylamido-2-methylpropanesulfonate and N-dodecylmethacrylamide with TX.
url http://dx.doi.org/10.1155/2011/617981
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AT takahirosato frontalanalysiscontinuouscapillaryelectrophoresisstudyontheinteractionofanamphiphilicalternatingcopolymerwithtritonx100
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