Frontal Analysis Continuous Capillary Electrophoresis Study on the Interaction of an Amphiphilic Alternating Copolymer with Triton X-100
The interaction of amphiphilic alternating copolymers of sodium maleate and dodecyl vinyl ether (Mal/C12) with a nonionic surfactant, Triton X-100 (TX), was investigated by frontal analysis continuous capillary electrophoresis (FACCE). The binding isotherms obtained from FACCE data were indicative...
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2011-01-01
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Series: | International Journal of Analytical Chemistry |
Online Access: | http://dx.doi.org/10.1155/2011/617981 |
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doaj-8c6db8e96df24ce29bb9401fb5581c7f2020-11-24T22:17:04ZengHindawi LimitedInternational Journal of Analytical Chemistry1687-87601687-87792011-01-01201110.1155/2011/617981617981Frontal Analysis Continuous Capillary Electrophoresis Study on the Interaction of an Amphiphilic Alternating Copolymer with Triton X-100Akihito Hashidzume0Takuya Shimomachi1Takahiro Sato2Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, JapanDepartment of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, JapanDepartment of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, JapanThe interaction of amphiphilic alternating copolymers of sodium maleate and dodecyl vinyl ether (Mal/C12) with a nonionic surfactant, Triton X-100 (TX), was investigated by frontal analysis continuous capillary electrophoresis (FACCE). The binding isotherms obtained from FACCE data were indicative of weak cooperative interaction for all the polymers examined. The cooperative interaction was also analyzed by the Hill model, and the results were compared with the previous results on the interaction of statistical copolymers of sodium 2-acrylamido-2-methylpropanesulfonate and N-dodecylmethacrylamide with TX.http://dx.doi.org/10.1155/2011/617981 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Akihito Hashidzume Takuya Shimomachi Takahiro Sato |
spellingShingle |
Akihito Hashidzume Takuya Shimomachi Takahiro Sato Frontal Analysis Continuous Capillary Electrophoresis Study on the Interaction of an Amphiphilic Alternating Copolymer with Triton X-100 International Journal of Analytical Chemistry |
author_facet |
Akihito Hashidzume Takuya Shimomachi Takahiro Sato |
author_sort |
Akihito Hashidzume |
title |
Frontal Analysis Continuous Capillary Electrophoresis Study on the Interaction of an Amphiphilic Alternating Copolymer with Triton X-100 |
title_short |
Frontal Analysis Continuous Capillary Electrophoresis Study on the Interaction of an Amphiphilic Alternating Copolymer with Triton X-100 |
title_full |
Frontal Analysis Continuous Capillary Electrophoresis Study on the Interaction of an Amphiphilic Alternating Copolymer with Triton X-100 |
title_fullStr |
Frontal Analysis Continuous Capillary Electrophoresis Study on the Interaction of an Amphiphilic Alternating Copolymer with Triton X-100 |
title_full_unstemmed |
Frontal Analysis Continuous Capillary Electrophoresis Study on the Interaction of an Amphiphilic Alternating Copolymer with Triton X-100 |
title_sort |
frontal analysis continuous capillary electrophoresis study on the interaction of an amphiphilic alternating copolymer with triton x-100 |
publisher |
Hindawi Limited |
series |
International Journal of Analytical Chemistry |
issn |
1687-8760 1687-8779 |
publishDate |
2011-01-01 |
description |
The interaction of amphiphilic alternating copolymers of sodium maleate and dodecyl vinyl ether (Mal/C12) with a nonionic surfactant, Triton X-100 (TX), was investigated by frontal analysis continuous capillary electrophoresis (FACCE). The binding isotherms obtained from FACCE data were indicative of weak cooperative interaction for all the polymers examined. The cooperative interaction was also analyzed by the Hill model, and the results were compared with the previous results on the interaction of statistical copolymers of sodium 2-acrylamido-2-methylpropanesulfonate and N-dodecylmethacrylamide with TX. |
url |
http://dx.doi.org/10.1155/2011/617981 |
work_keys_str_mv |
AT akihitohashidzume frontalanalysiscontinuouscapillaryelectrophoresisstudyontheinteractionofanamphiphilicalternatingcopolymerwithtritonx100 AT takuyashimomachi frontalanalysiscontinuouscapillaryelectrophoresisstudyontheinteractionofanamphiphilicalternatingcopolymerwithtritonx100 AT takahirosato frontalanalysiscontinuouscapillaryelectrophoresisstudyontheinteractionofanamphiphilicalternatingcopolymerwithtritonx100 |
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1725786685796515840 |