(Bis{2-[3-(2,4,6-trimethylbenzyl)imidazolin-2-yliden-1-yl-κC2]-4-methylphenyl}amido-κN)chloridopalladium(II)

(Bis{2-[3-(2,4,6-trimethylbenzyl)imidazolin-2-yliden-1-yl-κC2]-4-methylphenyl}amido-κN)chloridopalladium(II)

The coordination geometry about the Pd centre in the title compound, [Pd(C40H42N5)Cl], is approximately square-planar. The CNC pincer-type N-heterocyclic carbene ligand binds to the Pd atom in a tridentate fashion by the amido N atom and the two carbene atoms and generates two six-membered chelate r...

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Main Authors: Guan-Jun Cheng, Wei Wei, Chuang Zhou, Mei-Ming Luo
Format: Article
Language:English
Published: International Union of Crystallography 2010-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810002382
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spelling doaj-8c53299a756f416b868d3425fc9d9a962020-11-25T00:22:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-02-01662m198m19810.1107/S1600536810002382(Bis{2-[3-(2,4,6-trimethylbenzyl)imidazolin-2-yliden-1-yl-κC2]-4-methylphenyl}amido-κN)chloridopalladium(II)Guan-Jun ChengWei WeiChuang ZhouMei-Ming LuoThe coordination geometry about the Pd centre in the title compound, [Pd(C40H42N5)Cl], is approximately square-planar. The CNC pincer-type N-heterocyclic carbene ligand binds to the Pd atom in a tridentate fashion by the amido N atom and the two carbene atoms and generates two six-membered chelate rings, completing the coordination. http://scripts.iucr.org/cgi-bin/paper?S1600536810002382
collection DOAJ
language English
format Article
sources DOAJ
author Guan-Jun Cheng
Wei Wei
Chuang Zhou
Mei-Ming Luo
spellingShingle Guan-Jun Cheng
Wei Wei
Chuang Zhou
Mei-Ming Luo
(Bis{2-[3-(2,4,6-trimethylbenzyl)imidazolin-2-yliden-1-yl-κC2]-4-methylphenyl}amido-κN)chloridopalladium(II)
Acta Crystallographica Section E
author_facet Guan-Jun Cheng
Wei Wei
Chuang Zhou
Mei-Ming Luo
author_sort Guan-Jun Cheng
title (Bis{2-[3-(2,4,6-trimethylbenzyl)imidazolin-2-yliden-1-yl-κC2]-4-methylphenyl}amido-κN)chloridopalladium(II)
title_short (Bis{2-[3-(2,4,6-trimethylbenzyl)imidazolin-2-yliden-1-yl-κC2]-4-methylphenyl}amido-κN)chloridopalladium(II)
title_full (Bis{2-[3-(2,4,6-trimethylbenzyl)imidazolin-2-yliden-1-yl-κC2]-4-methylphenyl}amido-κN)chloridopalladium(II)
title_fullStr (Bis{2-[3-(2,4,6-trimethylbenzyl)imidazolin-2-yliden-1-yl-κC2]-4-methylphenyl}amido-κN)chloridopalladium(II)
title_full_unstemmed (Bis{2-[3-(2,4,6-trimethylbenzyl)imidazolin-2-yliden-1-yl-κC2]-4-methylphenyl}amido-κN)chloridopalladium(II)
title_sort (bis{2-[3-(2,4,6-trimethylbenzyl)imidazolin-2-yliden-1-yl-κc2]-4-methylphenyl}amido-κn)chloridopalladium(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-02-01
description The coordination geometry about the Pd centre in the title compound, [Pd(C40H42N5)Cl], is approximately square-planar. The CNC pincer-type N-heterocyclic carbene ligand binds to the Pd atom in a tridentate fashion by the amido N atom and the two carbene atoms and generates two six-membered chelate rings, completing the coordination.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810002382
work_keys_str_mv AT guanjuncheng bis23246trimethylbenzylimidazolin2yliden1ylamp954c24methylphenylamidoamp954nchloridopalladiumii
AT weiwei bis23246trimethylbenzylimidazolin2yliden1ylamp954c24methylphenylamidoamp954nchloridopalladiumii
AT chuangzhou bis23246trimethylbenzylimidazolin2yliden1ylamp954c24methylphenylamidoamp954nchloridopalladiumii
AT meimingluo bis23246trimethylbenzylimidazolin2yliden1ylamp954c24methylphenylamidoamp954nchloridopalladiumii
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