1,3-Dinitrosoimidazolidine
The title compound, C3H6N4O2, exhibits partial disorder with the refined occupancy ratios of the two components being 0.582 (5):0.418 (5). In the major component, the nitroso groups have a relative syn spatial arrangement [O=N...N=O pseudo-torsion angle = 1.1&#819...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812030796 |
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doaj-8b7d90b149a24131ba6fac462e946c8f2020-11-25T01:55:04ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-08-01688o2440o244010.1107/S16005368120307961,3-DinitrosoimidazolidineAugusto RiveraDiego QuirogaJaime Ríos-MottaMichal DušekKarla FejfarováThe title compound, C3H6N4O2, exhibits partial disorder with the refined occupancy ratios of the two components being 0.582 (5):0.418 (5). In the major component, the nitroso groups have a relative syn spatial arrangement [O=N...N=O pseudo-torsion angle = 1.1 (4)°], whereas the other component has an anti disposition [177.6 (1)°]. The N—N=O moieties are almost coplanar with a dihedral angle of 5.3 (3)°, while in the minor occupied set of atoms, this angle is 8 (1)°. In both components, the imidazolidine ring adopts a twisted conformation on the C—C bond and the crystal structure shows the strain of this ring according to the N—CH2—CH2—N torsion angles [25.9 (5) and −23.8 (7)°]. In the crystal, molecules are linked by weak C—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536812030796 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Augusto Rivera Diego Quiroga Jaime Ríos-Motta Michal Dušek Karla Fejfarová |
| spellingShingle |
Augusto Rivera Diego Quiroga Jaime Ríos-Motta Michal Dušek Karla Fejfarová 1,3-Dinitrosoimidazolidine Acta Crystallographica Section E |
| author_facet |
Augusto Rivera Diego Quiroga Jaime Ríos-Motta Michal Dušek Karla Fejfarová |
| author_sort |
Augusto Rivera |
| title |
1,3-Dinitrosoimidazolidine |
| title_short |
1,3-Dinitrosoimidazolidine |
| title_full |
1,3-Dinitrosoimidazolidine |
| title_fullStr |
1,3-Dinitrosoimidazolidine |
| title_full_unstemmed |
1,3-Dinitrosoimidazolidine |
| title_sort |
1,3-dinitrosoimidazolidine |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-08-01 |
| description |
The title compound, C3H6N4O2, exhibits partial disorder with the refined occupancy ratios of the two components being 0.582 (5):0.418 (5). In the major component, the nitroso groups have a relative syn spatial arrangement [O=N...N=O pseudo-torsion angle = 1.1 (4)°], whereas the other component has an anti disposition [177.6 (1)°]. The N—N=O moieties are almost coplanar with a dihedral angle of 5.3 (3)°, while in the minor occupied set of atoms, this angle is 8 (1)°. In both components, the imidazolidine ring adopts a twisted conformation on the C—C bond and the crystal structure shows the strain of this ring according to the N—CH2—CH2—N torsion angles [25.9 (5) and −23.8 (7)°]. In the crystal, molecules are linked by weak C—H...O hydrogen bonds. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812030796 |
| work_keys_str_mv |
AT augustorivera 13dinitrosoimidazolidine AT diegoquiroga 13dinitrosoimidazolidine AT jaimeramp237osmotta 13dinitrosoimidazolidine AT michalduamp353ek 13dinitrosoimidazolidine AT karlafejfarovamp225 13dinitrosoimidazolidine |
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