Di-μ-chlorido-bis({2-[(4-bromophenyl)iminomethyl]pyridine-κ2N,N′}chloridomercury(II))

Di-μ-chlorido-bis({2-[(4-bromophenyl)iminomethyl]pyridine-κ2N,N′}chloridomercury(II))

The unique HgII ion in the title centrosymmetric dinuclear complex, [Hg2Cl4(C12H9BrN2)2], is in a distorted trigonal–bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg&#8...

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Main Authors: Shabnam Pakravan, Mehdi Khalaj, Saeed Dehghanpour, Ali Mahmoudi
Format: Article
Language:English
Published: International Union of Crystallography 2009-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809025641
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spelling doaj-8b508b330fab4219a8e011ffabf709da2020-11-25T02:24:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658m889m88910.1107/S1600536809025641Di-μ-chlorido-bis({2-[(4-bromophenyl)iminomethyl]pyridine-κ2N,N′}chloridomercury(II))Shabnam PakravanMehdi KhalajSaeed DehghanpourAli MahmoudiThe unique HgII ion in the title centrosymmetric dinuclear complex, [Hg2Cl4(C12H9BrN2)2], is in a distorted trigonal–bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg—Cl bonds is significantly longer than the other. http://scripts.iucr.org/cgi-bin/paper?S1600536809025641
collection DOAJ
language English
format Article
sources DOAJ
author Shabnam Pakravan
Mehdi Khalaj
Saeed Dehghanpour
Ali Mahmoudi
spellingShingle Shabnam Pakravan
Mehdi Khalaj
Saeed Dehghanpour
Ali Mahmoudi
Di-μ-chlorido-bis({2-[(4-bromophenyl)iminomethyl]pyridine-κ2N,N′}chloridomercury(II))
Acta Crystallographica Section E
author_facet Shabnam Pakravan
Mehdi Khalaj
Saeed Dehghanpour
Ali Mahmoudi
author_sort Shabnam Pakravan
title Di-μ-chlorido-bis({2-[(4-bromophenyl)iminomethyl]pyridine-κ2N,N′}chloridomercury(II))
title_short Di-μ-chlorido-bis({2-[(4-bromophenyl)iminomethyl]pyridine-κ2N,N′}chloridomercury(II))
title_full Di-μ-chlorido-bis({2-[(4-bromophenyl)iminomethyl]pyridine-κ2N,N′}chloridomercury(II))
title_fullStr Di-μ-chlorido-bis({2-[(4-bromophenyl)iminomethyl]pyridine-κ2N,N′}chloridomercury(II))
title_full_unstemmed Di-μ-chlorido-bis({2-[(4-bromophenyl)iminomethyl]pyridine-κ2N,N′}chloridomercury(II))
title_sort di-μ-chlorido-bis({2-[(4-bromophenyl)iminomethyl]pyridine-κ2n,n′}chloridomercury(ii))
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-08-01
description The unique HgII ion in the title centrosymmetric dinuclear complex, [Hg2Cl4(C12H9BrN2)2], is in a distorted trigonal–bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg—Cl bonds is significantly longer than the other.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809025641
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AT mehdikhalaj diamp956chloridobis24bromophenyliminomethylpyridineamp9542nnamp8242chloridomercuryii
AT saeeddehghanpour diamp956chloridobis24bromophenyliminomethylpyridineamp9542nnamp8242chloridomercuryii
AT alimahmoudi diamp956chloridobis24bromophenyliminomethylpyridineamp9542nnamp8242chloridomercuryii
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