Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates

Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates

Synthesis of valuable polyene molecules under mild conditions and with good functional groups tolerance is of paramount importance. Here, the authors show the versatile copper-catalyzed successive dehydrogenation of a variety of organic substrates affording highly conjugated unsaturated products.

Bibliographic Details
Main Authors: Yaping Shang, Xiaoming Jie, Krishna Jonnada, Syeda Nahid Zafar, Weiping Su
Format: Article
Language:English
Published: Nature Publishing Group 2017-12-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-017-02381-8
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spelling doaj-8b31f860c29e4fcca0aed5e8acbe8a7a2021-05-11T07:23:07ZengNature Publishing GroupNature Communications2041-17232017-12-01811810.1038/s41467-017-02381-8Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediatesYaping Shang0Xiaoming Jie1Krishna Jonnada2Syeda Nahid Zafar3Weiping Su4State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesSynthesis of valuable polyene molecules under mild conditions and with good functional groups tolerance is of paramount importance. Here, the authors show the versatile copper-catalyzed successive dehydrogenation of a variety of organic substrates affording highly conjugated unsaturated products.https://doi.org/10.1038/s41467-017-02381-8
collection DOAJ
language English
format Article
sources DOAJ
author Yaping Shang
Xiaoming Jie
Krishna Jonnada
Syeda Nahid Zafar
Weiping Su
spellingShingle Yaping Shang
Xiaoming Jie
Krishna Jonnada
Syeda Nahid Zafar
Weiping Su
Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates
Nature Communications
author_facet Yaping Shang
Xiaoming Jie
Krishna Jonnada
Syeda Nahid Zafar
Weiping Su
author_sort Yaping Shang
title Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates
title_short Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates
title_full Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates
title_fullStr Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates
title_full_unstemmed Dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates
title_sort dehydrogenative desaturation-relay via formation of multicenter-stabilized radical intermediates
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2017-12-01
description Synthesis of valuable polyene molecules under mild conditions and with good functional groups tolerance is of paramount importance. Here, the authors show the versatile copper-catalyzed successive dehydrogenation of a variety of organic substrates affording highly conjugated unsaturated products.
url https://doi.org/10.1038/s41467-017-02381-8
work_keys_str_mv AT yapingshang dehydrogenativedesaturationrelayviaformationofmulticenterstabilizedradicalintermediates
AT xiaomingjie dehydrogenativedesaturationrelayviaformationofmulticenterstabilizedradicalintermediates
AT krishnajonnada dehydrogenativedesaturationrelayviaformationofmulticenterstabilizedradicalintermediates
AT syedanahidzafar dehydrogenativedesaturationrelayviaformationofmulticenterstabilizedradicalintermediates
AT weipingsu dehydrogenativedesaturationrelayviaformationofmulticenterstabilizedradicalintermediates
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