A synthetic, catalytic and theoretical investigation of an unsymmetrical SCN pincer palladacycle

A synthetic, catalytic and theoretical investigation of an unsymmetrical SCN pincer palladacycle

The SCN ligand 2-{3-[(methylsulfanyl)methyl]phenyl}pyridine, 1, has been synthesized starting from an initial Suzuki–Miyaura (SM) coupling between 3-((hydroxymethyl)phenyl)boronic acid and 2-bromopyridine. The C–H activation of 1 with in situ formed Pd(MeCN)4(BF4)2 has been studied and leads to a mi...

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Bibliographic Details
Main Authors: Gavin W. Roffe, Sarote Boonseng, Christine B. Baltus, Simon J. Coles, Iain J. Day, Rhiannon N. Jones, Neil J. Press, Mario Ruiz, Graham J. Tizzard, Hazel Cox, John Spencer
Format: Article
Language:English
Published: The Royal Society 2016-01-01
Series:Royal Society Open Science
Subjects:
palladium
c–h activation
calculations
Online Access:https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.150656

Internet

https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.150656

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