Bi aliovalent substitution in Li7La3Zr2O12 garnets: Structural and ionic conductivity effects

We report on the synthesis of cubic-phase garnet-type solid-state electrolytes based on Bi-doped Li7La3Zr2O12 (LLZO). Bi aliovalent substitution of Zr in LLZO utilizing the Pechini processing method is employed to synthesize Li7−xLa3Zr2−xBixO12 compounds. A strong dependence of the ionic conductivit...

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Bibliographic Details
Main Authors: Derek K. Schwanz, Andres Villa, Mahalingam Balasubramanian, Benjamin Helfrecht, Ernesto E. Marinero
Format: Article
Language:English
Published: AIP Publishing LLC 2020-03-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.5141764