Di-μ-oxido-bis({2-[(R,R)-(−)-(2-aminocyclohexyl)iminomethyl]-4-nitrophenolato-κ3N,N′,O}oxidovanadium(V)) dimethyl sulfoxide disolvate

Di-μ-oxido-bis({2-[(R,R)-(−)-(2-aminocyclohexyl)iminomethyl]-4-nitrophenolato-κ3N,N′,O}oxidovanadium(V)) dimethyl sulfoxide disolvate

The title compound, [V2(C13H16N3O3)2O4]·2C2H6OS, is a centrosymmetric dimeric complex solvated by two dimethyl sulfoxide molecules. Each VV atom is six-coordinated by one oxide group, two N atoms and one O atom from the tridentate Schiff base ligand, and by two additional bridging O atoms i...

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Main Authors: Grzegorz Romanowski, Michał Wera, Artur Sikorski
Format: Article
Language:English
Published: International Union of Crystallography 2009-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808038762
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spelling doaj-8b134fa6f6a343cf91e79c81362b63b12020-11-25T01:09:42ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651m25m2610.1107/S1600536808038762Di-μ-oxido-bis({2-[(R,R)-(−)-(2-aminocyclohexyl)iminomethyl]-4-nitrophenolato-κ3N,N′,O}oxidovanadium(V)) dimethyl sulfoxide disolvateGrzegorz RomanowskiMichał WeraArtur SikorskiThe title compound, [V2(C13H16N3O3)2O4]·2C2H6OS, is a centrosymmetric dimeric complex solvated by two dimethyl sulfoxide molecules. Each VV atom is six-coordinated by one oxide group, two N atoms and one O atom from the tridentate Schiff base ligand, and by two additional bridging O atoms in a distorted octahedral coordination geometry. Three atoms of the cyclohexane ring are each disordered over two sites, with occupancy factors of 0.501 (10) and 0.499 (10). C—H...O and N—H...O hydrogen bonds link the dimers and solvent molecules into a supramolecular network.http://scripts.iucr.org/cgi-bin/paper?S1600536808038762
collection DOAJ
language English
format Article
sources DOAJ
author Grzegorz Romanowski
Michał Wera
Artur Sikorski
spellingShingle Grzegorz Romanowski
Michał Wera
Artur Sikorski
Di-μ-oxido-bis({2-[(R,R)-(−)-(2-aminocyclohexyl)iminomethyl]-4-nitrophenolato-κ3N,N′,O}oxidovanadium(V)) dimethyl sulfoxide disolvate
Acta Crystallographica Section E
author_facet Grzegorz Romanowski
Michał Wera
Artur Sikorski
author_sort Grzegorz Romanowski
title Di-μ-oxido-bis({2-[(R,R)-(−)-(2-aminocyclohexyl)iminomethyl]-4-nitrophenolato-κ3N,N′,O}oxidovanadium(V)) dimethyl sulfoxide disolvate
title_short Di-μ-oxido-bis({2-[(R,R)-(−)-(2-aminocyclohexyl)iminomethyl]-4-nitrophenolato-κ3N,N′,O}oxidovanadium(V)) dimethyl sulfoxide disolvate
title_full Di-μ-oxido-bis({2-[(R,R)-(−)-(2-aminocyclohexyl)iminomethyl]-4-nitrophenolato-κ3N,N′,O}oxidovanadium(V)) dimethyl sulfoxide disolvate
title_fullStr Di-μ-oxido-bis({2-[(R,R)-(−)-(2-aminocyclohexyl)iminomethyl]-4-nitrophenolato-κ3N,N′,O}oxidovanadium(V)) dimethyl sulfoxide disolvate
title_full_unstemmed Di-μ-oxido-bis({2-[(R,R)-(−)-(2-aminocyclohexyl)iminomethyl]-4-nitrophenolato-κ3N,N′,O}oxidovanadium(V)) dimethyl sulfoxide disolvate
title_sort di-μ-oxido-bis({2-[(r,r)-(−)-(2-aminocyclohexyl)iminomethyl]-4-nitrophenolato-κ3n,n′,o}oxidovanadium(v)) dimethyl sulfoxide disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-01-01
description The title compound, [V2(C13H16N3O3)2O4]·2C2H6OS, is a centrosymmetric dimeric complex solvated by two dimethyl sulfoxide molecules. Each VV atom is six-coordinated by one oxide group, two N atoms and one O atom from the tridentate Schiff base ligand, and by two additional bridging O atoms in a distorted octahedral coordination geometry. Three atoms of the cyclohexane ring are each disordered over two sites, with occupancy factors of 0.501 (10) and 0.499 (10). C—H...O and N—H...O hydrogen bonds link the dimers and solvent molecules into a supramolecular network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808038762
work_keys_str_mv AT grzegorzromanowski di956oxidobis2rr87222aminocyclohexyliminomethyl4nitrophenolato9543nn8242ooxidovanadiumvdimethylsulfoxidedisolvate
AT micha322wera di956oxidobis2rr87222aminocyclohexyliminomethyl4nitrophenolato9543nn8242ooxidovanadiumvdimethylsulfoxidedisolvate
AT artursikorski di956oxidobis2rr87222aminocyclohexyliminomethyl4nitrophenolato9543nn8242ooxidovanadiumvdimethylsulfoxidedisolvate
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