Recent advances in direct C–H arylation: Methodology, selectivity and mechanism in oxazole series

Recent advances in direct C–H arylation: Methodology, selectivity and mechanism in oxazole series

Catalytic direct (hetero)arylation of (hetero)arenes is an attractive alternative to traditional Kumada, Stille, Negishi and Suzuki–Miyaura cross-coupling reactions, notably as it avoids the prior preparation and isolation of (hetero)arylmetals. Developments of this methodology in the oxazole series...

Full description

Bibliographic Details
Main Authors: Cécile Verrier, Pierrik Lassalas, Laure Théveau, Guy Quéguiner, François Trécourt, Francis Marsais, Christophe Hoarau
Format: Article
Language:English
Published: Beilstein-Institut 2011-11-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
ate complex
catalytic direct arylation
mechanism
oxazole
selectivity
transition-metal catalysis
Online Access:https://doi.org/10.3762/bjoc.7.187
Description
Summary:Catalytic direct (hetero)arylation of (hetero)arenes is an attractive alternative to traditional Kumada, Stille, Negishi and Suzuki–Miyaura cross-coupling reactions, notably as it avoids the prior preparation and isolation of (hetero)arylmetals. Developments of this methodology in the oxazole series are reviewed in this article. Methodologies, selectivity, mechanism and future aspects are presented.
ISSN:1860-5397

Similar Items