Preparation, Characterization, and Thermal Degradation Studies of p-Nitrophenol-Based Copolymer

Polycondensation reaction was employed to synthesize a new copolymer resin (p-NP-4,4′-MDA-F) from p-nitrophenol (p-NP) and 4,4′-methylene dianiline (4,4′-MDA) with formaldehyde (F) in presence of 2 M hydrochloric acid as a catalyst at 130±1°C. The resin was characterized by elemental analysis and s...

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Bibliographic Details
Main Authors: Pawan P. Kalbende, Mangesh V. Tarase, Anil B. Zade
Format: Article
Language:English
Published: Hindawi Limited 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/846327
Description
Summary:Polycondensation reaction was employed to synthesize a new copolymer resin (p-NP-4,4′-MDA-F) from p-nitrophenol (p-NP) and 4,4′-methylene dianiline (4,4′-MDA) with formaldehyde (F) in presence of 2 M hydrochloric acid as a catalyst at 130±1°C. The resin was characterized by elemental analysis and spectral studies such as UV-visible, FT-IR, and 1H-NMR spectra which were used to confine the most probable structure of synthesized copolymer. Thermal degradation pattern and kinetics have been investigated by thermogravimetric analysis. Thermal degradation curve have been studied with minute detail for each degradation step. Friedman, Chang, Sharp-Wentworth, Freeman-Carroll, and Coat-Redfern methods have been implemented in order to compute the kinetic parameters, that is, thermal activation energy (Ea), order of reaction (n), and frequency factor (z).
ISSN:2090-9063
2090-9071