Rhodium(I)-Complexes Catalyzed 1,4-Conjugate Addition of Arylzinc Chlorides to N-Boc-4-pyridone

Rhodium(I)-Complexes Catalyzed 1,4-Conjugate Addition of Arylzinc Chlorides to N-Boc-4-pyridone

Rhodium(I)-complexes catalyzed the 1,4-conjugate addition of arylzinc chlorides to N-Boc-4-pyridone in the presence of chlorotrimethylsilane (TMSCl). A combination of [RhCl(C2H4)2]2 and BINAP was determined to be the most effective catalyst to promote the 1,4-conjugate addition reactions of arylzinc...

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Bibliographic Details
Main Authors: Fenghai Guo, Matthew A. McGilvary, Malcolm C. Jeffries, Briana N. Graves, Shekinah A. Graham, Yuelin Wu
Format: Article
Language:English
Published: MDPI AG 2017-05-01
Series:Molecules
Subjects:
N-boc-4-pyridone
rhodium (I)-complexes
conjugate addition
2,3-dihydropyridones
Online Access:http://www.mdpi.com/1420-3049/22/5/723

Internet

http://www.mdpi.com/1420-3049/22/5/723

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