Controlled Radical Polymerization toward Ultra-High Molecular Weight by Rationally Designed Borane Radical Initiators

Summary: Ultra-high-molecular-weight (UHMW) polymers can display outstanding properties; however, it is challenging to synthesize UHMW polymers by using external free radical initiators. To address this, here, we report the ration design and adoption of B-alkylcatecholborane (RBCat) as a radical ini...

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Bibliographic Details
Main Authors: Yinling Wang, Qianyi Wang, Xiangcheng Pan
Format: Article
Language:English
Published: Elsevier 2020-06-01
Series:Cell Reports Physical Science
Subjects:
CRP
Online Access:http://www.sciencedirect.com/science/article/pii/S2666386420300680