Synthesis of Certain Poly[bis(benzylidene)] Esters and Investigation on their Photocrosslinkability

Synthesis of Certain Poly[bis(benzylidene)] Esters and Investigation on their Photocrosslinkability

Random copolyesters were synthesized directly from respective diacids and diols with diphenylchlorophosphate (DPCP) as a polycondensation agent. These polymers were characterized by FT-IR and NMR spectrometry. Interestingly, they were observed to possess photocrosslinkability which was established u...

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Main Authors: D. Roop Singh, S. Vasanthi, J. Arul Moli
Format: Article
Language:English
Published: Hindawi Limited 2012-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2012/656493
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spelling doaj-89358c8fc53346a6a42caa71ead783f12020-11-25T00:07:14ZengHindawi LimitedE-Journal of Chemistry0973-49452090-98102012-01-019114514810.1155/2012/656493Synthesis of Certain Poly[bis(benzylidene)] Esters and Investigation on their PhotocrosslinkabilityD. Roop Singh0S. Vasanthi1J. Arul Moli2Post-Graduate and Research Department of Chemistry, Presidency College (Autonomous), Chennai-600 005, IndiaPost-Graduate and Research Department of Chemistry, Presidency College (Autonomous), Chennai-600 005, IndiaPost-Graduate and Research Department of Chemistry, Presidency College (Autonomous), Chennai-600 005, IndiaRandom copolyesters were synthesized directly from respective diacids and diols with diphenylchlorophosphate (DPCP) as a polycondensation agent. These polymers were characterized by FT-IR and NMR spectrometry. Interestingly, they were observed to possess photocrosslinkability which was established using scanning electron microscopy by UV irradiation experiments. Photocrosslinkable polymers have significant applications in the field of non-linear optics, in the generation of photoresists and photorefractive materials.http://dx.doi.org/10.1155/2012/656493
collection DOAJ
language English
format Article
sources DOAJ
author D. Roop Singh
S. Vasanthi
J. Arul Moli
spellingShingle D. Roop Singh
S. Vasanthi
J. Arul Moli
Synthesis of Certain Poly[bis(benzylidene)] Esters and Investigation on their Photocrosslinkability
E-Journal of Chemistry
author_facet D. Roop Singh
S. Vasanthi
J. Arul Moli
author_sort D. Roop Singh
title Synthesis of Certain Poly[bis(benzylidene)] Esters and Investigation on their Photocrosslinkability
title_short Synthesis of Certain Poly[bis(benzylidene)] Esters and Investigation on their Photocrosslinkability
title_full Synthesis of Certain Poly[bis(benzylidene)] Esters and Investigation on their Photocrosslinkability
title_fullStr Synthesis of Certain Poly[bis(benzylidene)] Esters and Investigation on their Photocrosslinkability
title_full_unstemmed Synthesis of Certain Poly[bis(benzylidene)] Esters and Investigation on their Photocrosslinkability
title_sort synthesis of certain poly[bis(benzylidene)] esters and investigation on their photocrosslinkability
publisher Hindawi Limited
series E-Journal of Chemistry
issn 0973-4945
2090-9810
publishDate 2012-01-01
description Random copolyesters were synthesized directly from respective diacids and diols with diphenylchlorophosphate (DPCP) as a polycondensation agent. These polymers were characterized by FT-IR and NMR spectrometry. Interestingly, they were observed to possess photocrosslinkability which was established using scanning electron microscopy by UV irradiation experiments. Photocrosslinkable polymers have significant applications in the field of non-linear optics, in the generation of photoresists and photorefractive materials.
url http://dx.doi.org/10.1155/2012/656493
work_keys_str_mv AT droopsingh synthesisofcertainpolybisbenzylideneestersandinvestigationontheirphotocrosslinkability
AT svasanthi synthesisofcertainpolybisbenzylideneestersandinvestigationontheirphotocrosslinkability
AT jarulmoli synthesisofcertainpolybisbenzylideneestersandinvestigationontheirphotocrosslinkability
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