(OC-6-35)-(2,2′-Bipyridine-κ2N,N′)dimethyl(3-sulfidopropionato-κ2S,O)platinum(IV)

(OC-6-35)-(2,2′-Bipyridine-κ2N,N′)dimethyl(3-sulfidopropionato-κ2S,O)platinum(IV)

The title complex, [Pt(CH3)2(SCH2CH2CO2)(C10H8N2)], is formed by the unusual oxidative addition of the disulfide, R2S2 (R = CH2CH2CO2H), to (2,2′-bipyridine)dimethylplatinum(II) with elimination of RSH. The product contains an unusual six-membered thiolate–carboxylate che...

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Main Authors: Matthew S. McCready, Richard J. Puddephatt
Format: Article
Language:English
Published: International Union of Crystallography 2011-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811013626
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spelling doaj-8908bcc42e9a45d6ab4fe79e8983da972020-11-24T22:15:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-05-01675m604m60510.1107/S1600536811013626(OC-6-35)-(2,2′-Bipyridine-κ2N,N′)dimethyl(3-sulfidopropionato-κ2S,O)platinum(IV)Matthew S. McCreadyRichard J. PuddephattThe title complex, [Pt(CH3)2(SCH2CH2CO2)(C10H8N2)], is formed by the unusual oxidative addition of the disulfide, R2S2 (R = CH2CH2CO2H), to (2,2′-bipyridine)dimethylplatinum(II) with elimination of RSH. The product contains an unusual six-membered thiolate–carboxylate chelate ring. This slightly distorted octahedral complex exhibits cis angles ranging from 77.55 (11) to 97.30 (8)° due to the presence of the thiolate–carboxylate chelate ring and the constrained bipyridine group. The crystal packing appears to be controlled by a combination of π-stacking [centroid–centroid distance = 3.611 (2) Å] and C—H...O interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536811013626
collection DOAJ
language English
format Article
sources DOAJ
author Matthew S. McCready
Richard J. Puddephatt
spellingShingle Matthew S. McCready
Richard J. Puddephatt
(OC-6-35)-(2,2′-Bipyridine-κ2N,N′)dimethyl(3-sulfidopropionato-κ2S,O)platinum(IV)
Acta Crystallographica Section E
author_facet Matthew S. McCready
Richard J. Puddephatt
author_sort Matthew S. McCready
title (OC-6-35)-(2,2′-Bipyridine-κ2N,N′)dimethyl(3-sulfidopropionato-κ2S,O)platinum(IV)
title_short (OC-6-35)-(2,2′-Bipyridine-κ2N,N′)dimethyl(3-sulfidopropionato-κ2S,O)platinum(IV)
title_full (OC-6-35)-(2,2′-Bipyridine-κ2N,N′)dimethyl(3-sulfidopropionato-κ2S,O)platinum(IV)
title_fullStr (OC-6-35)-(2,2′-Bipyridine-κ2N,N′)dimethyl(3-sulfidopropionato-κ2S,O)platinum(IV)
title_full_unstemmed (OC-6-35)-(2,2′-Bipyridine-κ2N,N′)dimethyl(3-sulfidopropionato-κ2S,O)platinum(IV)
title_sort (oc-6-35)-(2,2′-bipyridine-κ2n,n′)dimethyl(3-sulfidopropionato-κ2s,o)platinum(iv)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-05-01
description The title complex, [Pt(CH3)2(SCH2CH2CO2)(C10H8N2)], is formed by the unusual oxidative addition of the disulfide, R2S2 (R = CH2CH2CO2H), to (2,2′-bipyridine)dimethylplatinum(II) with elimination of RSH. The product contains an unusual six-membered thiolate–carboxylate chelate ring. This slightly distorted octahedral complex exhibits cis angles ranging from 77.55 (11) to 97.30 (8)° due to the presence of the thiolate–carboxylate chelate ring and the constrained bipyridine group. The crystal packing appears to be controlled by a combination of π-stacking [centroid–centroid distance = 3.611 (2) Å] and C—H...O interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811013626
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AT richardjpuddephatt oc63522amp8242bipyridineamp9542nnamp8242dimethyl3sulfidopropionatoamp9542soplatinumiv
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