(OC-6-35)-(2,2′-Bipyridine-κ2N,N′)dimethyl(3-sulfidopropionato-κ2S,O)platinum(IV)
The title complex, [Pt(CH3)2(SCH2CH2CO2)(C10H8N2)], is formed by the unusual oxidative addition of the disulfide, R2S2 (R = CH2CH2CO2H), to (2,2′-bipyridine)dimethylplatinum(II) with elimination of RSH. The product contains an unusual six-membered thiolate–carboxylate che...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2011-05-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811013626 |
Summary: | The title complex, [Pt(CH3)2(SCH2CH2CO2)(C10H8N2)], is formed by the unusual oxidative addition of the disulfide, R2S2 (R = CH2CH2CO2H), to (2,2′-bipyridine)dimethylplatinum(II) with elimination of RSH. The product contains an unusual six-membered thiolate–carboxylate chelate ring. This slightly distorted octahedral complex exhibits cis angles ranging from 77.55 (11) to 97.30 (8)° due to the presence of the thiolate–carboxylate chelate ring and the constrained bipyridine group. The crystal packing appears to be controlled by a combination of π-stacking [centroid–centroid distance = 3.611 (2) Å] and C—H...O interactions. |
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ISSN: | 1600-5368 |