Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight

Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight

Organocatalytic atom transfer radical polymerization (O-ATRP) is attractive due to its metal-free nature but catalysts are rarely applied at a low loading. Here the authors introduce a catalyst design logic based on heteroatom-doping of polycyclic arenes, which led to the discovery of oxygen-doped a...

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Main Authors: Qiang Ma, Jinshuai Song, Xun Zhang, Yu Jiang, Li Ji, Saihu Liao
Format: Article
Language:English
Published: Nature Publishing Group 2021-01-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-020-20645-8
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spelling doaj-88be05f482a64236a23650a990086e8b2021-01-24T12:11:46ZengNature Publishing GroupNature Communications2041-17232021-01-011211810.1038/s41467-020-20645-8Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlightQiang Ma0Jinshuai Song1Xun Zhang2Yu Jiang3Li Ji4Saihu Liao5Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou UniversityCollege of Chemistry and Molecular Engineering, Zhengzhou UniversityKey Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou UniversityKey Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou UniversityGrubbs Institute, Southern University of Science and TechnologyKey Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou UniversityOrganocatalytic atom transfer radical polymerization (O-ATRP) is attractive due to its metal-free nature but catalysts are rarely applied at a low loading. Here the authors introduce a catalyst design logic based on heteroatom-doping of polycyclic arenes, which led to the discovery of oxygen-doped anthanthrene as an organic photoredox catalysts for O-ATRP.https://doi.org/10.1038/s41467-020-20645-8
collection DOAJ
language English
format Article
sources DOAJ
author Qiang Ma
Jinshuai Song
Xun Zhang
Yu Jiang
Li Ji
Saihu Liao
spellingShingle Qiang Ma
Jinshuai Song
Xun Zhang
Yu Jiang
Li Ji
Saihu Liao
Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight
Nature Communications
author_facet Qiang Ma
Jinshuai Song
Xun Zhang
Yu Jiang
Li Ji
Saihu Liao
author_sort Qiang Ma
title Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight
title_short Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight
title_full Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight
title_fullStr Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight
title_full_unstemmed Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight
title_sort metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2021-01-01
description Organocatalytic atom transfer radical polymerization (O-ATRP) is attractive due to its metal-free nature but catalysts are rarely applied at a low loading. Here the authors introduce a catalyst design logic based on heteroatom-doping of polycyclic arenes, which led to the discovery of oxygen-doped anthanthrene as an organic photoredox catalysts for O-ATRP.
url https://doi.org/10.1038/s41467-020-20645-8
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AT jinshuaisong metalfreeatomtransferradicalpolymerizationwithppmcatalystloadingundersunlight
AT xunzhang metalfreeatomtransferradicalpolymerizationwithppmcatalystloadingundersunlight
AT yujiang metalfreeatomtransferradicalpolymerizationwithppmcatalystloadingundersunlight
AT liji metalfreeatomtransferradicalpolymerizationwithppmcatalystloadingundersunlight
AT saihuliao metalfreeatomtransferradicalpolymerizationwithppmcatalystloadingundersunlight
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