Preparation, Characterization and Electrochemical Lithium Insertion Into the New Organic–Inorganic Poly(3,4-Ethylene Dioxythiophene)/V2O5 Hybrid

Preparation, Characterization and Electrochemical Lithium Insertion Into the New Organic–Inorganic Poly(3,4-Ethylene Dioxythiophene)/V2O5 Hybrid

Poly(3,4-ethylene dioxythiophene) (PEDOT) has been inserted between the layers of crystalline V2O5 via the in situ polymerization of EDOT within the framework of the oxyde. The insertion increases the bidimensionality of the V2O5 host by the layer separation but results in a random layer stacking s...

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Main Authors: Chai-Won Kwon, A. Vadivel Murugan, Guy Campet
Format: Article
Language:English
Published: Hindawi Limited 2003-01-01
Series:Active and Passive Electronic Components
Online Access:http://dx.doi.org/10.1080/1042015031000073904
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spelling doaj-88adc0539c604bc3bcd987209af06a8d2020-11-25T00:01:33ZengHindawi LimitedActive and Passive Electronic Components0882-75161563-50312003-01-0126317118310.1080/1042015031000073904Preparation, Characterization and Electrochemical Lithium Insertion Into the New Organic–Inorganic Poly(3,4-Ethylene Dioxythiophene)/V2O5 HybridChai-Won Kwon0A. Vadivel Murugan1Guy Campet2Institut de Chimie de la Matiére Condensèe de Bordeaux du CNRS, 87 Avenue du Dr. A. Schweitzer, Pessac Cedex 33608, FranceCentre for Materials for Electronics Technology, Ministry of Communication and Information Technology, Govt. of India, Panchawati, Off-Pashan Road, Pune 411008, IndiaInstitut de Chimie de la Matiére Condensèe de Bordeaux du CNRS, 87 Avenue du Dr. A. Schweitzer, Pessac Cedex 33608, FrancePoly(3,4-ethylene dioxythiophene) (PEDOT) has been inserted between the layers of crystalline V2O5 via the in situ polymerization of EDOT within the framework of the oxyde. The insertion increases the bidimensionality of the V2O5 host by the layer separation but results in a random layer stacking structure, leading to broadening of the energy state distribution. According to electrochemical measurements, the hybrids showed reversible specific capacities up to ∼330 mAh/g at 15mA/g between 2 and 4.4V vs. Li+ /Li.http://dx.doi.org/10.1080/1042015031000073904
collection DOAJ
language English
format Article
sources DOAJ
author Chai-Won Kwon
A. Vadivel Murugan
Guy Campet
spellingShingle Chai-Won Kwon
A. Vadivel Murugan
Guy Campet
Preparation, Characterization and Electrochemical Lithium Insertion Into the New Organic–Inorganic Poly(3,4-Ethylene Dioxythiophene)/V2O5 Hybrid
Active and Passive Electronic Components
author_facet Chai-Won Kwon
A. Vadivel Murugan
Guy Campet
author_sort Chai-Won Kwon
title Preparation, Characterization and Electrochemical Lithium Insertion Into the New Organic–Inorganic Poly(3,4-Ethylene Dioxythiophene)/V2O5 Hybrid
title_short Preparation, Characterization and Electrochemical Lithium Insertion Into the New Organic–Inorganic Poly(3,4-Ethylene Dioxythiophene)/V2O5 Hybrid
title_full Preparation, Characterization and Electrochemical Lithium Insertion Into the New Organic–Inorganic Poly(3,4-Ethylene Dioxythiophene)/V2O5 Hybrid
title_fullStr Preparation, Characterization and Electrochemical Lithium Insertion Into the New Organic–Inorganic Poly(3,4-Ethylene Dioxythiophene)/V2O5 Hybrid
title_full_unstemmed Preparation, Characterization and Electrochemical Lithium Insertion Into the New Organic–Inorganic Poly(3,4-Ethylene Dioxythiophene)/V2O5 Hybrid
title_sort preparation, characterization and electrochemical lithium insertion into the new organic–inorganic poly(3,4-ethylene dioxythiophene)/v2o5 hybrid
publisher Hindawi Limited
series Active and Passive Electronic Components
issn 0882-7516
1563-5031
publishDate 2003-01-01
description Poly(3,4-ethylene dioxythiophene) (PEDOT) has been inserted between the layers of crystalline V2O5 via the in situ polymerization of EDOT within the framework of the oxyde. The insertion increases the bidimensionality of the V2O5 host by the layer separation but results in a random layer stacking structure, leading to broadening of the energy state distribution. According to electrochemical measurements, the hybrids showed reversible specific capacities up to ∼330 mAh/g at 15mA/g between 2 and 4.4V vs. Li+ /Li.
url http://dx.doi.org/10.1080/1042015031000073904
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AT avadivelmurugan preparationcharacterizationandelectrochemicallithiuminsertionintotheneworganicinorganicpoly34ethylenedioxythiophenev2o5hybrid
AT guycampet preparationcharacterizationandelectrochemicallithiuminsertionintotheneworganicinorganicpoly34ethylenedioxythiophenev2o5hybrid
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