Development of Amylose- and β-Cyclodextrin-Based Chiral Fluorescent Sensors Bearing Terthienyl Pendants

Development of Amylose- and β-Cyclodextrin-Based Chiral Fluorescent Sensors Bearing Terthienyl Pendants

Phenylcarbamate derivatives of amylose and β-cyclodextrin show excellent chiral recognition when used as chiral stationary phases (CSPs) for high-performance liquid chromatography. To open up new possibilities of carbohydrate-based materials, we developed chiral fluorescent sensors based on amylose...

Full description

Bibliographic Details
Main Authors:	Tomoyuki Ikai, Changsik Yun, Yutaka Kojima, Daisuke Suzuki, Katsuhiro Maeda, Shigeyoshi Kanoh
Format:	Article
Language:	English
Published:	MDPI AG 2016-11-01
Series:	Molecules
Subjects:	carbohydrates chirality fluorescent sensor helix higher-order structure polysaccharides
Online Access:	http://www.mdpi.com/1420-3049/21/11/1518

Similar Items

Synthesis of Optically Active Poly(diphenylacetylene)s Using Polymer Reactions and an Evaluation of Their Chiral Recognition Abilities as Chiral Stationary Phases for HPLC
by: Katsuhiro Maeda, et al.
Published: (2016-11-01)

Synthesis of Amphiphilic Block Copolymers Containing Chiral Polythiophene Chains and Their Micelle Formation and Chiroptical Properties
by: Daisuke Hirose, et al.
Published: (2018-06-01)

Temperature-Triggered Switchable Helix-Helix Inversion of Poly(phenylacetylene) Bearing l-Valine Ethyl Ester Pendants and Its Chiral Recognition Ability
by: Yanli Zhou, et al.
Published: (2016-11-01)

The Breaking of Symmetry Leads to Chirality in Cucurbituril-Type Hosts
by: Riina Aav, et al.
Published: (2018-04-01)

Characterization of Hidden Chirality: Two-Fold Helicity in β-Strands
by: Toshiyuki Sasaki, et al.
Published: (2019-04-01)

Chiral liquid crystals from carbohydrates.
Published: (1995)

N-Centered Chiral Self-Sorting and Supramolecular Helix of Tröger's Base-Based Dimeric Macrocycles in Crystalline State
by: Yuan Chen, et al.
Published: (2019-05-01)

Enantioseparation Using Cellulose Tris(3,5-dimethylphenylcarbamate) as Chiral Stationary Phase for HPLC: Influence of Molecular Weight of Cellulose
by: Yuji Okada, et al.
Published: (2016-11-01)

Qualitative Analysis of the Helical Electronic Energy of Inherently Chiral Calix[4]arenes: An Approach to Effectively Assign Their Absolute Configuration
by: Shuang Zheng, et al.
Published: (2014-06-01)

Generation of Supramolecular Chirality around Twofold Rotational or Helical Axes in Crystalline Assemblies of Achiral Components
by: Mikiji Miyata, et al.
Published: (2015-10-01)

Phosphated cyclodextrins as water-soluble chiral NMR solvating agents for cationic compounds
by: Cira Mollings Puentes, et al.
Published: (2017-01-01)

Protein Helical Structures: Defining Handedness and Localization Features
by: Alla E. Sidorova, et al.
Published: (2021-05-01)

Synthesis of new chiral auxiliares from carbohydrates for Et2AlCl-promoted Diels-Alder reactions
by: Ferreira Vitor F., et al.
Published: (2000-01-01)

Polysaccharide- and β-Cyclodextrin-Based Chiral Selectors for Enantiomer Resolution: Recent Developments and Applications
by: Cuong Viet Bui, et al.
Published: (2021-07-01)

CHIRAL SEPARATION OF CETIRIZINE ENANTIOMERS BY CYCLODEXTRIN MEDIATED CAPILLARY ELECTROPHORESIS
by: Gabriel Hancu, et al.
Published: (2014-10-01)

The Use of Dual Cyclodextrin Chiral Selector Systems in the Enantioseparation of Pharmaceuticals by Capillary Electrophoresis: An Overview
by: Gabriel Hancu, et al.
Published: (2021-04-01)

Part 1, Oligosaccharide synthesis on a hyperbranched polymer as soluble support ; Part 2, Photoresponsive conformational equilibria of chiral, helically folded dendrons /
by: Kantchev, Assen B.
Published: (2001)

Enhanced Chiral Recognition by Cyclodextrin Dimers
by: Bart Jan Ravoo, et al.
Published: (2011-07-01)

Cyclodextrine Screening for the Chiral Separation of Amlodipine Enantiomers by Capillary Electrophoresis
by: Gabriel Hancu, et al.
Published: (2015-03-01)

Chiral Stationary Phases for Liquid Chromatography Based on Chitin- and Chitosan-Derived Marine Polysaccharides
by: João Ribeiro, et al.
Published: (2017-09-01)

Chiral Auxiliaries and Chirogenesis
Published: (2021)

A protocol to replace dedication to either normal phase or polar organic mode for chiral stationary phases containing amylose tris(3,5-dimethylphenylcarbamate)
by: Eke, Z., et al.
Published: (2022)

Chiral Plasmonic Biosensors
by: Vladimir E. Bochenkov, et al.
Published: (2018-12-01)

Tuning the helical sense and elongation of polymers through the combined action of the two components of tetraalkylammonium-anion salts
by: Seila Leiras, et al.
Published: (2021-08-01)

Venlafaxine Chiral Separation by Capillary Electrophoresis Using Cyclodextrin Derivatives as Chiral Selector and Experimental Design Method Optimization
by: Andreea Milan, et al.
Published: (2020-05-01)

Terthienyl carbene complexes
by: Moeng, Mmushi Moses
Published: (2013)

Recognition and Sensing of Chiral Organic Molecules by Chiral Porphyrinoids: A Review
by: Gabriele Travagliante, et al.
Published: (2021-08-01)

Chiral Self-Assembly of Porphyrins Induced by Chiral Carbon Dots
by: Xiaowei Liu, et al.
Published: (2020-08-01)

Enantioseparation and Determination of Mephedrone and Its Metabolites by Capillary Electrophoresis Using Cyclodextrins as Chiral Selectors
by: Pavel Řezanka, et al.
Published: (2020-06-01)

Chiral recognition of ephedrine: Hydrophilic polymers bearing β-cyclodextrin moieties as chiral sensitive host molecules
by: Sabrina Gingter, et al.
Published: (2011-11-01)

Chiral Graphene Hybrid Materials: Structures, Properties, and Chiral Applications
by: Biao Zhao, et al.
Published: (2021-04-01)

Effect of carbon source (carbohydrate) on the chemical structure of water-soluble mushroom polysaccharides produced by submerged fermentation.
Published: (2005)

Spectroscopic and chromatographic investigation of derivatized cyclodextrins
by: Gahm, Kyung-Hyun
Published: (2009)

Chirality Construction from Preferred π-π Stacks of Achiral Azobenzene Units in Polymer: Chiral Induction, Transfer and Memory
by: Tengfei Miao, et al.
Published: (2018-06-01)

Chiral Separations on HPLC Derivatized Polysaccharide CSPs: Temperature, Mobile Phase and Chiral Recognition Mechanism Studies
by: Cabusas, Maria Elena Ybarbia III
Published: (2014)

Chiral recognition of macromolecules with cyclodextrins: pH- and thermosensitive copolymers from N-isopropylacrylamide and N-acryloyl-D/L-phenylalanine and their inclusion complexes with cyclodextrins
by: Sabrina Gingter, et al.
Published: (2011-02-01)

Helicene-Based Chiral Auxiliaries and Chirogenesis
by: Mohammed Hasan, et al.
Published: (2017-12-01)

Alkaline degradation of amylose: a kinetic mode
by: Geddes, Daniel J.
Published: (2005)

The use of arabinose in asymmetric Diels-Alder reaction.
Published: (1995)

[Rh(L-alaninate)(1,5-Cyclooctadiene)] Catalyzed Helix-Sense-Selective Polymerizations of Achiral Phenylacetylenes
by: Qingyu Wang, et al.
Published: (2018-11-01)