Synthesis, Crystal Structures, and Antimicrobial Activity of Zinc(II) and Manganese(II) Complexes Derived from N’-(1-(pyridin-2-yl)ethylidene)isonicotinohydrazide

Synthesis, Crystal Structures, and Antimicrobial Activity of Zinc(II) and Manganese(II) Complexes Derived from N’-(1-(pyridin-2-yl)ethylidene)isonicotinohydrazide

Two mononuclear zinc(II) and manganese(II) compounds, [ZnL2] (1) and [MnL(HL)]ClO4 (2), where L is the monoanionic form of N’-(1-(pyridin-2-yl)ethylidene)isonicotinohydrazide (HL), and HL is the zwitterionic form of HL, have been prepared and characterized by elemental analyses, IR and UV-Vis spectr...

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Main Authors: Ling-Wei Xue, Hui-Jie Zhang, Pan-Pan Wang
Format: Article
Language:English
Published: Slovenian Chemical Society 2019-02-01
Series:Acta Chimica Slovenica
Subjects:
Hydrazone
Zinc complex
Manganese complex
Crystal structure
Antimicrobial activity
Online Access:https://journals.matheo.si/index.php/ACSi/article/view/4773
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spelling doaj-88588805bf9e4c5883ae3270c36162cf2020-11-24T21:34:57ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552019-02-0166119019510.17344/acsi.2018.4773673Synthesis, Crystal Structures, and Antimicrobial Activity of Zinc(II) and Manganese(II) Complexes Derived from N’-(1-(pyridin-2-yl)ethylidene)isonicotinohydrazideLing-Wei Xue0Hui-Jie ZhangPan-Pan WangPingdingshan UniversityTwo mononuclear zinc(II) and manganese(II) compounds, [ZnL2] (1) and [MnL(HL)]ClO4 (2), where L is the monoanionic form of N’-(1-(pyridin-2-yl)ethylidene)isonicotinohydrazide (HL), and HL is the zwitterionic form of HL, have been prepared and characterized by elemental analyses, IR and UV-Vis spectroscopy, and single-crystal X-ray crystallographic determination. Compound 1 contains a neutral [ZnL2] complex molecule. Compound 2 contains a [MnL(HL)]+ complex cation and one perchlorate anion. The metal atoms in the complexes are in octahedral coordination. The hydrazone ligands coordinate to the metal atoms through the pyridine N, imine N, and enolate O atoms. The compounds were investigated for their antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans.https://journals.matheo.si/index.php/ACSi/article/view/4773HydrazoneZinc complexManganese complexCrystal structureAntimicrobial activity
collection DOAJ
language English
format Article
sources DOAJ
author Ling-Wei Xue
Hui-Jie Zhang
Pan-Pan Wang
spellingShingle Ling-Wei Xue
Hui-Jie Zhang
Pan-Pan Wang
Synthesis, Crystal Structures, and Antimicrobial Activity of Zinc(II) and Manganese(II) Complexes Derived from N’-(1-(pyridin-2-yl)ethylidene)isonicotinohydrazide
Acta Chimica Slovenica
Hydrazone
Zinc complex
Manganese complex
Crystal structure
Antimicrobial activity
author_facet Ling-Wei Xue
Hui-Jie Zhang
Pan-Pan Wang
author_sort Ling-Wei Xue
title Synthesis, Crystal Structures, and Antimicrobial Activity of Zinc(II) and Manganese(II) Complexes Derived from N’-(1-(pyridin-2-yl)ethylidene)isonicotinohydrazide
title_short Synthesis, Crystal Structures, and Antimicrobial Activity of Zinc(II) and Manganese(II) Complexes Derived from N’-(1-(pyridin-2-yl)ethylidene)isonicotinohydrazide
title_full Synthesis, Crystal Structures, and Antimicrobial Activity of Zinc(II) and Manganese(II) Complexes Derived from N’-(1-(pyridin-2-yl)ethylidene)isonicotinohydrazide
title_fullStr Synthesis, Crystal Structures, and Antimicrobial Activity of Zinc(II) and Manganese(II) Complexes Derived from N’-(1-(pyridin-2-yl)ethylidene)isonicotinohydrazide
title_full_unstemmed Synthesis, Crystal Structures, and Antimicrobial Activity of Zinc(II) and Manganese(II) Complexes Derived from N’-(1-(pyridin-2-yl)ethylidene)isonicotinohydrazide
title_sort synthesis, crystal structures, and antimicrobial activity of zinc(ii) and manganese(ii) complexes derived from n’-(1-(pyridin-2-yl)ethylidene)isonicotinohydrazide
publisher Slovenian Chemical Society
series Acta Chimica Slovenica
issn 1318-0207
1580-3155
publishDate 2019-02-01
description Two mononuclear zinc(II) and manganese(II) compounds, [ZnL2] (1) and [MnL(HL)]ClO4 (2), where L is the monoanionic form of N’-(1-(pyridin-2-yl)ethylidene)isonicotinohydrazide (HL), and HL is the zwitterionic form of HL, have been prepared and characterized by elemental analyses, IR and UV-Vis spectroscopy, and single-crystal X-ray crystallographic determination. Compound 1 contains a neutral [ZnL2] complex molecule. Compound 2 contains a [MnL(HL)]+ complex cation and one perchlorate anion. The metal atoms in the complexes are in octahedral coordination. The hydrazone ligands coordinate to the metal atoms through the pyridine N, imine N, and enolate O atoms. The compounds were investigated for their antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans.
topic Hydrazone
Zinc complex
Manganese complex
Crystal structure
Antimicrobial activity
url https://journals.matheo.si/index.php/ACSi/article/view/4773
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AT huijiezhang synthesiscrystalstructuresandantimicrobialactivityofzinciiandmanganeseiicomplexesderivedfromn1pyridin2ylethylideneisonicotinohydrazide
AT panpanwang synthesiscrystalstructuresandantimicrobialactivityofzinciiandmanganeseiicomplexesderivedfromn1pyridin2ylethylideneisonicotinohydrazide
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