Poly[[tris(μ2-4,4′-bipyridine N,N′-dioxide)hexanitratodieuropium(III)] dichloromethane disolvate]

Poly[[tris(μ2-4,4′-bipyridine N,N′-dioxide)hexanitratodieuropium(III)] dichloromethane disolvate]

The title one-dimensional coordination network, {[Eu2(NO3)6(C10H8N2O2)3]·2CH2Cl2}n, is isostructural with the previously reported Tb and Tl coordination networks and to its Gd analog. The EuIII cation is coordinated in a distorted tricapped trigonal-prismatic fashion by nine O atoms fro...

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Main Authors: Adam J. Dillner, Cassandra P. Lilly, Jacqueline M. Knaust
Format: Article
Language:English
Published: International Union of Crystallography 2010-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810033246
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spelling doaj-881042944c864f06b1ae742c53fadd5b2020-11-25T01:53:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669m1156m115710.1107/S1600536810033246Poly[[tris(μ2-4,4′-bipyridine N,N′-dioxide)hexanitratodieuropium(III)] dichloromethane disolvate]Adam J. DillnerCassandra P. LillyJacqueline M. KnaustThe title one-dimensional coordination network, {[Eu2(NO3)6(C10H8N2O2)3]·2CH2Cl2}n, is isostructural with the previously reported Tb and Tl coordination networks and to its Gd analog. The EuIII cation is coordinated in a distorted tricapped trigonal-prismatic fashion by nine O atoms from three bridging 4,4′-bipyridine N,N′-dioxide ligands and three chelating nitrate anions. None of the atoms lie on a special position, but there is an inversion center located between the rings of one of the ligands. The network topology is ladder-like, and each ladder interacts with six neighboring ladders through C—H...O hydrogen bonds. The packing motif of the ladders allows for the formation of channels that run parallel to the a axis; these channels are filled with CH2Cl2 solvent molecules that interact with the ladders through C—H...O hydrogen bonds. http://scripts.iucr.org/cgi-bin/paper?S1600536810033246
collection DOAJ
language English
format Article
sources DOAJ
author Adam J. Dillner
Cassandra P. Lilly
Jacqueline M. Knaust
spellingShingle Adam J. Dillner
Cassandra P. Lilly
Jacqueline M. Knaust
Poly[[tris(μ2-4,4′-bipyridine N,N′-dioxide)hexanitratodieuropium(III)] dichloromethane disolvate]
Acta Crystallographica Section E
author_facet Adam J. Dillner
Cassandra P. Lilly
Jacqueline M. Knaust
author_sort Adam J. Dillner
title Poly[[tris(μ2-4,4′-bipyridine N,N′-dioxide)hexanitratodieuropium(III)] dichloromethane disolvate]
title_short Poly[[tris(μ2-4,4′-bipyridine N,N′-dioxide)hexanitratodieuropium(III)] dichloromethane disolvate]
title_full Poly[[tris(μ2-4,4′-bipyridine N,N′-dioxide)hexanitratodieuropium(III)] dichloromethane disolvate]
title_fullStr Poly[[tris(μ2-4,4′-bipyridine N,N′-dioxide)hexanitratodieuropium(III)] dichloromethane disolvate]
title_full_unstemmed Poly[[tris(μ2-4,4′-bipyridine N,N′-dioxide)hexanitratodieuropium(III)] dichloromethane disolvate]
title_sort poly[[tris(μ2-4,4′-bipyridine n,n′-dioxide)hexanitratodieuropium(iii)] dichloromethane disolvate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-09-01
description The title one-dimensional coordination network, {[Eu2(NO3)6(C10H8N2O2)3]·2CH2Cl2}n, is isostructural with the previously reported Tb and Tl coordination networks and to its Gd analog. The EuIII cation is coordinated in a distorted tricapped trigonal-prismatic fashion by nine O atoms from three bridging 4,4′-bipyridine N,N′-dioxide ligands and three chelating nitrate anions. None of the atoms lie on a special position, but there is an inversion center located between the rings of one of the ligands. The network topology is ladder-like, and each ladder interacts with six neighboring ladders through C—H...O hydrogen bonds. The packing motif of the ladders allows for the formation of channels that run parallel to the a axis; these channels are filled with CH2Cl2 solvent molecules that interact with the ladders through C—H...O hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810033246
work_keys_str_mv AT adamjdillner polytrisamp956244amp8242bipyridinennamp8242dioxidehexanitratodieuropiumiiidichloromethanedisolvate
AT cassandraplilly polytrisamp956244amp8242bipyridinennamp8242dioxidehexanitratodieuropiumiiidichloromethanedisolvate
AT jacquelinemknaust polytrisamp956244amp8242bipyridinennamp8242dioxidehexanitratodieuropiumiiidichloromethanedisolvate
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