Diaquabis(5-methylpyrazine-2-carboxylato-κ2N1,O2)cadmium

Diaquabis(5-methylpyrazine-2-carboxylato-κ2N1,O2)cadmium

In the title compound, [Cd(C6H5N2O2)2(H2O)2], the CdII ion is coordinated in a severely distorted octahedral geometry. The N atoms are cis to each other, while the water O atoms and ligand O atoms are mutually trans. The crystal structure is stabilized by a network of O—H...O, O&am...

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Main Authors: Matías López-Rodríguez, Alejandro Cárdenas, Joselyn Albanez, Iván Brito
Format: Article
Language:English
Published: International Union of Crystallography 2011-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811035045
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spelling doaj-87bb03b388d7490e8f567fcd663e76ba2020-11-24T21:28:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1339m134010.1107/S1600536811035045Diaquabis(5-methylpyrazine-2-carboxylato-κ2N1,O2)cadmiumMatías López-RodríguezAlejandro CárdenasJoselyn AlbanezIván BritoIn the title compound, [Cd(C6H5N2O2)2(H2O)2], the CdII ion is coordinated in a severely distorted octahedral geometry. The N atoms are cis to each other, while the water O atoms and ligand O atoms are mutually trans. The crystal structure is stabilized by a network of O—H...O, O—H...N and C—H...O hydrogen bonds and π–π stacking interactions [centroid–centroid distances = 3.730 (3) and 3.652 (3) Å] between the 5-methylpyrazine-2-carboxylate ligands. The structure is isotypic with the manganese analog.http://scripts.iucr.org/cgi-bin/paper?S1600536811035045
collection DOAJ
language English
format Article
sources DOAJ
author Matías López-Rodríguez
Alejandro Cárdenas
Joselyn Albanez
Iván Brito
spellingShingle Matías López-Rodríguez
Alejandro Cárdenas
Joselyn Albanez
Iván Brito
Diaquabis(5-methylpyrazine-2-carboxylato-κ2N1,O2)cadmium
Acta Crystallographica Section E
author_facet Matías López-Rodríguez
Alejandro Cárdenas
Joselyn Albanez
Iván Brito
author_sort Matías López-Rodríguez
title Diaquabis(5-methylpyrazine-2-carboxylato-κ2N1,O2)cadmium
title_short Diaquabis(5-methylpyrazine-2-carboxylato-κ2N1,O2)cadmium
title_full Diaquabis(5-methylpyrazine-2-carboxylato-κ2N1,O2)cadmium
title_fullStr Diaquabis(5-methylpyrazine-2-carboxylato-κ2N1,O2)cadmium
title_full_unstemmed Diaquabis(5-methylpyrazine-2-carboxylato-κ2N1,O2)cadmium
title_sort diaquabis(5-methylpyrazine-2-carboxylato-κ2n1,o2)cadmium
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-10-01
description In the title compound, [Cd(C6H5N2O2)2(H2O)2], the CdII ion is coordinated in a severely distorted octahedral geometry. The N atoms are cis to each other, while the water O atoms and ligand O atoms are mutually trans. The crystal structure is stabilized by a network of O—H...O, O—H...N and C—H...O hydrogen bonds and π–π stacking interactions [centroid–centroid distances = 3.730 (3) and 3.652 (3) Å] between the 5-methylpyrazine-2-carboxylate ligands. The structure is isotypic with the manganese analog.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811035045
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