Synthesis, Characterization and Mechanical Properties of Novel Bio-Based Polyurethane Foams Using Cellulose-Derived Polyol for Chain Extension and Cellulose Citrate as a Thickener Additive

A novel series of bio-based polyurethane composite foams was prepared, employing a cellulose-derived polyol for chain extension and cellulose-citrate as a thickener additive. The utilized polyol was obtained from the reduction reaction of cellulose-derived bio-oil through the use of sodium borohydri...

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Bibliographic Details
Main Authors: Loredana Maiuolo, Fabrizio Olivito, Vincenzo Algieri, Paola Costanzo, Antonio Jiritano, Matteo Antonio Tallarida, Antonio Tursi, Corradino Sposato, Andrea Feo, Antonio De Nino
Format: Article
Language:English
Published: MDPI AG 2021-08-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/13/16/2802
Description
Summary:A novel series of bio-based polyurethane composite foams was prepared, employing a cellulose-derived polyol for chain extension and cellulose-citrate as a thickener additive. The utilized polyol was obtained from the reduction reaction of cellulose-derived bio-oil through the use of sodium borohydride and iodine. Primarily, we produced both rigid and flexible polyurethane foams through chain extension of the prepolymers. Secondly, we investigated the role of cellulose citrate as a polyurethane additive to improve the mechanical properties of the realized composite materials. The products were characterized by FT-IR spectroscopy and their morphologies were analysed by SEM. Mechanical tests were evaluated to open new perspectives towards different applications.
ISSN:2073-4360