4,12-Bis(2,2-dibromovinyl)[2.2]paracyclophane
In the title compound, C20H16Br4, both vinylic substituents were introduced by a Corey–Fuchs reaction using 4,12-diformyl[2.2]paracyclophane as starting material. The title compound may be used as a valuable precursor for the synthesis of diethynyl[2.2]paracyclophane. The title molecul...
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| Language: | English |
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International Union of Crystallography
2009-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809002475 |
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doaj-87a9934ea9474d14b4aeb59dcc96d2e62020-11-25T02:15:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-03-01653o528o52810.1107/S16005368090024754,12-Bis(2,2-dibromovinyl)[2.2]paracyclophaneIn the title compound, C20H16Br4, both vinylic substituents were introduced by a Corey–Fuchs reaction using 4,12-diformyl[2.2]paracyclophane as starting material. The title compound may be used as a valuable precursor for the synthesis of diethynyl[2.2]paracyclophane. The title molecule is centrosymmetric with a crystallographic center of inversion between the centers of the two phenyl rings. A strong tilting is observed with an interplanar angle between the best aromatic plane and the vinyl plane of 49.4 (5)°. No significant intermolecular interactions are found in the crystal. http://scripts.iucr.org/cgi-bin/paper?S1600536809002475 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| title |
4,12-Bis(2,2-dibromovinyl)[2.2]paracyclophane |
| spellingShingle |
4,12-Bis(2,2-dibromovinyl)[2.2]paracyclophane Acta Crystallographica Section E |
| title_short |
4,12-Bis(2,2-dibromovinyl)[2.2]paracyclophane |
| title_full |
4,12-Bis(2,2-dibromovinyl)[2.2]paracyclophane |
| title_fullStr |
4,12-Bis(2,2-dibromovinyl)[2.2]paracyclophane |
| title_full_unstemmed |
4,12-Bis(2,2-dibromovinyl)[2.2]paracyclophane |
| title_sort |
4,12-bis(2,2-dibromovinyl)[2.2]paracyclophane |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2009-03-01 |
| description |
In the title compound, C20H16Br4, both vinylic substituents were introduced by a Corey–Fuchs reaction using 4,12-diformyl[2.2]paracyclophane as starting material. The title compound may be used as a valuable precursor for the synthesis of diethynyl[2.2]paracyclophane. The title molecule is centrosymmetric with a crystallographic center of inversion between the centers of the two phenyl rings. A strong tilting is observed with an interplanar angle between the best aromatic plane and the vinyl plane of 49.4 (5)°. No significant intermolecular interactions are found in the crystal. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809002475 |
| _version_ |
1724896753177591808 |