Bis(N-isopropyl-N-methyldithiocarbamato-κ2S,S′)(1,10-phenanthroline-κ2N,N′)zinc

Bis(N-isopropyl-N-methyldithiocarbamato-κ2S,S′)(1,10-phenanthroline-κ2N,N′)zinc

The ZnII atom in the title compound, [Zn(C5H10NS2)2(C12H8N2)], exists in a distorted cis-octahedral N2S4 donor set defined by two chelating dithiocarbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak C...

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Bibliographic Details
Main Authors: Nor Asiken Abdul Wahab, Ibrahim Baba, Mohamed Ibrahim Mohamed Tahir, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2011-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811012499
Description
Summary:The ZnII atom in the title compound, [Zn(C5H10NS2)2(C12H8N2)], exists in a distorted cis-octahedral N2S4 donor set defined by two chelating dithiocarbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak C—H...S, C—H...π(ZnS2C) and π–π [ring centroid distance between centrosymmetrically related pyridyl rings = 3.5955 (13) Å] interactions.
ISSN:1600-5368

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