CdS Nanoplates Modification as a Platform for Synthesis of Blue-Emitting Nanoparticles

In this paper, the study of surface modification of two-dimensional (2D), non-luminescent CdS nanoplates (NPLs) by thiol-containing ligands is presented. We show that a process of twophase transfers with appropriate ligand exchange transforms non-luminescent NPLs into spherical CdS nanoparticles (NP...

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Main Authors:	Anna Lesiak, Mateusz Banski, Hanna Woznica, Andrzej Żak, Joanna Cabaj, Artur Podhorodecki
Format:	Article
Language:	English
Published:	MDPI AG 2021-06-01
Series:	International Journal of Molecular Sciences
Subjects:	3-mercaptopropionic acid blue emitting quantum dots <span style="font-variant: small-caps">d</span>-penicillamine ligand exchange CdS nanoplatelets phase transfer
Online Access:	https://www.mdpi.com/1422-0067/22/12/6477

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spelling	doaj-86c9d1c62c434defb1221473bfb7f23b2021-07-01T00:23:20ZengMDPI AGInternational Journal of Molecular Sciences1661-65961422-00672021-06-01226477647710.3390/ijms22126477CdS Nanoplates Modification as a Platform for Synthesis of Blue-Emitting NanoparticlesAnna Lesiak0Mateusz Banski1Hanna Woznica2Andrzej Żak3Joanna Cabaj4Artur Podhorodecki5Faculty of Fundamental Problems of Technology, Wroclaw University of Science and Technology, Wybrzeze Wyspianskiego 27, 50–370 Wroclaw, PolandFaculty of Fundamental Problems of Technology, Wroclaw University of Science and Technology, Wybrzeze Wyspianskiego 27, 50–370 Wroclaw, PolandFaculty of Fundamental Problems of Technology, Wroclaw University of Science and Technology, Wybrzeze Wyspianskiego 27, 50–370 Wroclaw, PolandElectron Microscopy Laboratory, Faculty of Mechanical Engineering, Wroclaw University of Science and Technology, Wybrzeze Wyspianskiego 27, 50–370 Wroclaw, PolandFaculty of Chemistry, Wroclaw University of Science and Technology, Wybrzeze Wyspianskiego 27, 50–370 Wroclaw, PolandFaculty of Fundamental Problems of Technology, Wroclaw University of Science and Technology, Wybrzeze Wyspianskiego 27, 50–370 Wroclaw, PolandIn this paper, the study of surface modification of two-dimensional (2D), non-luminescent CdS nanoplates (NPLs) by thiol-containing ligands is presented. We show that a process of twophase transfers with appropriate ligand exchange transforms non-luminescent NPLs into spherical CdS nanoparticles (NPs) exhibiting a blue photoluminescence with exceptionally high quantum yield ~90%. In the process, transfer from inorganic solvent to water is performed, with appropriately selected ligand molecules and pH values (forward phase transfer), which produces NPs with modified size and shape. Then, in reverse phase transfer, NPs are transferred back to toluene due to surface modification by combined Cd (OL)<sub>2</sub> and Cd (Ac)<sub>2</sub>. As a result, spherical NPs are formed (average diameter between 4 and 6 nm) with PL QY as high as 90%. This is unique for core only CdS NPs without inorganic shell.https://www.mdpi.com/1422-0067/22/12/64773-mercaptopropionic acidblue emitting quantum dots<span style="font-variant: small-caps">d</span>-penicillamineligand exchangeCdS nanoplateletsphase transfer
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Anna Lesiak Mateusz Banski Hanna Woznica Andrzej Żak Joanna Cabaj Artur Podhorodecki
spellingShingle	Anna Lesiak Mateusz Banski Hanna Woznica Andrzej Żak Joanna Cabaj Artur Podhorodecki CdS Nanoplates Modification as a Platform for Synthesis of Blue-Emitting Nanoparticles International Journal of Molecular Sciences 3-mercaptopropionic acid blue emitting quantum dots <span style="font-variant: small-caps">d</span>-penicillamine ligand exchange CdS nanoplatelets phase transfer
author_facet	Anna Lesiak Mateusz Banski Hanna Woznica Andrzej Żak Joanna Cabaj Artur Podhorodecki
author_sort	Anna Lesiak
title	CdS Nanoplates Modification as a Platform for Synthesis of Blue-Emitting Nanoparticles
title_short	CdS Nanoplates Modification as a Platform for Synthesis of Blue-Emitting Nanoparticles
title_full	CdS Nanoplates Modification as a Platform for Synthesis of Blue-Emitting Nanoparticles
title_fullStr	CdS Nanoplates Modification as a Platform for Synthesis of Blue-Emitting Nanoparticles
title_full_unstemmed	CdS Nanoplates Modification as a Platform for Synthesis of Blue-Emitting Nanoparticles
title_sort	cds nanoplates modification as a platform for synthesis of blue-emitting nanoparticles
publisher	MDPI AG
series	International Journal of Molecular Sciences
issn	1661-6596 1422-0067
publishDate	2021-06-01
description	In this paper, the study of surface modification of two-dimensional (2D), non-luminescent CdS nanoplates (NPLs) by thiol-containing ligands is presented. We show that a process of twophase transfers with appropriate ligand exchange transforms non-luminescent NPLs into spherical CdS nanoparticles (NPs) exhibiting a blue photoluminescence with exceptionally high quantum yield ~90%. In the process, transfer from inorganic solvent to water is performed, with appropriately selected ligand molecules and pH values (forward phase transfer), which produces NPs with modified size and shape. Then, in reverse phase transfer, NPs are transferred back to toluene due to surface modification by combined Cd (OL)<sub>2</sub> and Cd (Ac)<sub>2</sub>. As a result, spherical NPs are formed (average diameter between 4 and 6 nm) with PL QY as high as 90%. This is unique for core only CdS NPs without inorganic shell.
topic	3-mercaptopropionic acid blue emitting quantum dots <span style="font-variant: small-caps">d</span>-penicillamine ligand exchange CdS nanoplatelets phase transfer
url	https://www.mdpi.com/1422-0067/22/12/6477
work_keys_str_mv	AT annalesiak cdsnanoplatesmodificationasaplatformforsynthesisofblueemittingnanoparticles AT mateuszbanski cdsnanoplatesmodificationasaplatformforsynthesisofblueemittingnanoparticles AT hannawoznica cdsnanoplatesmodificationasaplatformforsynthesisofblueemittingnanoparticles AT andrzejzak cdsnanoplatesmodificationasaplatformforsynthesisofblueemittingnanoparticles AT joannacabaj cdsnanoplatesmodificationasaplatformforsynthesisofblueemittingnanoparticles AT arturpodhorodecki cdsnanoplatesmodificationasaplatformforsynthesisofblueemittingnanoparticles
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CdS Nanoplates Modification as a Platform for Synthesis of Blue-Emitting Nanoparticles

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