A SnO<sub>2</sub>/CeO<sub>2</sub> Nano-Composite Catalyst for Alizarin Dye Removal from Aqueous Solutions

A new SnO<sub>2</sub>/CeO<sub>2</sub> nano-composite catalyst was synthesized, characterized and used for the removal of alizarin dyes from aqueous solutions. The composite material was prepared using a precipitation method. X-ray powder diffractometry (XRD), high resolution...

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Main Authors: Saad S. M. Hassan, Ayman H. Kamel, Amr A. Hassan, Abd El-Galil E. Amr, Heba Abd El-Naby, Elsayed A. Elsayed
Format: Article
Language:English
Published: MDPI AG 2020-02-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/10/2/254
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spelling doaj-86827159b7e14a699cf701fa805d93642020-11-25T01:42:38ZengMDPI AGNanomaterials2079-49912020-02-0110225410.3390/nano10020254nano10020254A SnO<sub>2</sub>/CeO<sub>2</sub> Nano-Composite Catalyst for Alizarin Dye Removal from Aqueous SolutionsSaad S. M. Hassan0Ayman H. Kamel1Amr A. Hassan2Abd El-Galil E. Amr3Heba Abd El-Naby4Elsayed A. Elsayed5Chemistry Department, Faculty of Science, Ain Shams University, Abbasia 11566, Cairo, EgyptChemistry Department, Faculty of Science, Ain Shams University, Abbasia 11566, Cairo, EgyptChemistry Department, Faculty of Science, Ain Shams University, Abbasia 11566, Cairo, EgyptPharmaceutical Chemistry Department, Drug Exploration &amp; Development Chair (DEDC), College of Pharmacy, King Saud University, Riyadh 11451, Saudi ArabiaChemistry Department, Faculty of Science, Ain Shams University, Abbasia 11566, Cairo, EgyptBioproducts Research Department, Zoology Department, Faculty of Science, King Saud University, Riyadh 11451, Saudi ArabiaA new SnO<sub>2</sub>/CeO<sub>2</sub> nano-composite catalyst was synthesized, characterized and used for the removal of alizarin dyes from aqueous solutions. The composite material was prepared using a precipitation method. X-ray powder diffractometry (XRD), high resolution transmission electron microscopy (HR-TEM), Brunauer&#8722;Emmett&#8722;Teller methodology (BET) and Fourier Transform Infrared Spectrometry (ATR-FTIR) were utilized for the characterization of the prepared composite. The prepared nano-composite revealed high affinity for the adsorption and decomposition of alizarin dyes. The adsorption capacity under different experimental conditions (adsorbate concentration, contact time, adsorbent dose and pH) was examined. Under optimized experimental conditions, the removal of alizarin yellow, alizarin red and alizarin-3-methylimino-diacetic acid dyes from aqueous solutions was about 96.4%,87.8% and 97.3%, respectively. The adsorption isotherms agreed with the models of Langmuir, Freundlich and Temkin isotherms.https://www.mdpi.com/2079-4991/10/2/254tin oxide/cerium oxidenano-compositeadsorption of dyesalizarin dyes removal
collection DOAJ
language English
format Article
sources DOAJ
author Saad S. M. Hassan
Ayman H. Kamel
Amr A. Hassan
Abd El-Galil E. Amr
Heba Abd El-Naby
Elsayed A. Elsayed
spellingShingle Saad S. M. Hassan
Ayman H. Kamel
Amr A. Hassan
Abd El-Galil E. Amr
Heba Abd El-Naby
Elsayed A. Elsayed
A SnO<sub>2</sub>/CeO<sub>2</sub> Nano-Composite Catalyst for Alizarin Dye Removal from Aqueous Solutions
Nanomaterials
tin oxide/cerium oxide
nano-composite
adsorption of dyes
alizarin dyes removal
author_facet Saad S. M. Hassan
Ayman H. Kamel
Amr A. Hassan
Abd El-Galil E. Amr
Heba Abd El-Naby
Elsayed A. Elsayed
author_sort Saad S. M. Hassan
title A SnO<sub>2</sub>/CeO<sub>2</sub> Nano-Composite Catalyst for Alizarin Dye Removal from Aqueous Solutions
title_short A SnO<sub>2</sub>/CeO<sub>2</sub> Nano-Composite Catalyst for Alizarin Dye Removal from Aqueous Solutions
title_full A SnO<sub>2</sub>/CeO<sub>2</sub> Nano-Composite Catalyst for Alizarin Dye Removal from Aqueous Solutions
title_fullStr A SnO<sub>2</sub>/CeO<sub>2</sub> Nano-Composite Catalyst for Alizarin Dye Removal from Aqueous Solutions
title_full_unstemmed A SnO<sub>2</sub>/CeO<sub>2</sub> Nano-Composite Catalyst for Alizarin Dye Removal from Aqueous Solutions
title_sort sno<sub>2</sub>/ceo<sub>2</sub> nano-composite catalyst for alizarin dye removal from aqueous solutions
publisher MDPI AG
series Nanomaterials
issn 2079-4991
publishDate 2020-02-01
description A new SnO<sub>2</sub>/CeO<sub>2</sub> nano-composite catalyst was synthesized, characterized and used for the removal of alizarin dyes from aqueous solutions. The composite material was prepared using a precipitation method. X-ray powder diffractometry (XRD), high resolution transmission electron microscopy (HR-TEM), Brunauer&#8722;Emmett&#8722;Teller methodology (BET) and Fourier Transform Infrared Spectrometry (ATR-FTIR) were utilized for the characterization of the prepared composite. The prepared nano-composite revealed high affinity for the adsorption and decomposition of alizarin dyes. The adsorption capacity under different experimental conditions (adsorbate concentration, contact time, adsorbent dose and pH) was examined. Under optimized experimental conditions, the removal of alizarin yellow, alizarin red and alizarin-3-methylimino-diacetic acid dyes from aqueous solutions was about 96.4%,87.8% and 97.3%, respectively. The adsorption isotherms agreed with the models of Langmuir, Freundlich and Temkin isotherms.
topic tin oxide/cerium oxide
nano-composite
adsorption of dyes
alizarin dyes removal
url https://www.mdpi.com/2079-4991/10/2/254
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