Poly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate]

The CoII atom in the title complex, {[Co(C10H8N2)(H2O)4](C8H4O4)}n, is coordinated by two N atoms of two bipyridine ligands and four O atoms of four water molecules in an octahedral geometry. The one-dimensional [Co(C10H8N2)(H2O)4]2+ cation chain is further extended into a supramolecular network via...

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Main Author: Haiyun Xu
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807064045
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spelling doaj-8664c9eb84c047408900f90f2d037bdc2020-11-25T02:46:35ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m103m10310.1107/S1600536807064045Poly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate]Haiyun XuThe CoII atom in the title complex, {[Co(C10H8N2)(H2O)4](C8H4O4)}n, is coordinated by two N atoms of two bipyridine ligands and four O atoms of four water molecules in an octahedral geometry. The one-dimensional [Co(C10H8N2)(H2O)4]2+ cation chain is further extended into a supramolecular network via O–H...O hydrogen-bond interactions. The Co atom lies on a twofold rotation axis; another twofold rotation axis passes through the carboxylate carbon atoms and the attached ring C atoms.http://scripts.iucr.org/cgi-bin/paper?S1600536807064045
collection DOAJ
language English
format Article
sources DOAJ
author Haiyun Xu
spellingShingle Haiyun Xu
Poly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate]
Acta Crystallographica Section E
author_facet Haiyun Xu
author_sort Haiyun Xu
title Poly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate]
title_short Poly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate]
title_full Poly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate]
title_fullStr Poly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate]
title_full_unstemmed Poly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate]
title_sort poly[[[tetraaquacobalt(ii)]-μ-bipyridine] terephthalate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-01-01
description The CoII atom in the title complex, {[Co(C10H8N2)(H2O)4](C8H4O4)}n, is coordinated by two N atoms of two bipyridine ligands and four O atoms of four water molecules in an octahedral geometry. The one-dimensional [Co(C10H8N2)(H2O)4]2+ cation chain is further extended into a supramolecular network via O–H...O hydrogen-bond interactions. The Co atom lies on a twofold rotation axis; another twofold rotation axis passes through the carboxylate carbon atoms and the attached ring C atoms.
url http://scripts.iucr.org/cgi-bin/paper?S1600536807064045
work_keys_str_mv AT haiyunxu polytetraaquacobaltii956bipyridineterephthalate
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