Poly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate]
The CoII atom in the title complex, {[Co(C10H8N2)(H2O)4](C8H4O4)}n, is coordinated by two N atoms of two bipyridine ligands and four O atoms of four water molecules in an octahedral geometry. The one-dimensional [Co(C10H8N2)(H2O)4]2+ cation chain is further extended into a supramolecular network via...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807064045 |
| Summary: | The CoII atom in the title complex, {[Co(C10H8N2)(H2O)4](C8H4O4)}n, is coordinated by two N atoms of two bipyridine ligands and four O atoms of four water molecules in an octahedral geometry. The one-dimensional [Co(C10H8N2)(H2O)4]2+ cation chain is further extended into a supramolecular network via O–H...O hydrogen-bond interactions. The Co atom lies on a twofold rotation axis; another twofold rotation axis passes through the carboxylate carbon atoms and the attached ring C atoms. |
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| ISSN: | 1600-5368 |