catena-Poly[[(5-carboxy-2H-1,2,3-triazole-4-carboxylato-κ2N3,O4)sodium]-di-μ-aqua-κ4O:O]

In the title coordination polymer, [Na(C4H2N3O4)(H2O)2]n, the NaI atom is six-coordinated by one O atom and one N atom from a 2H-1,2,3-triazole-4-carboxy-5-carboxylate ligand and four O atoms from four water molecules, forming a distorted octahedal geometry. The NaI atoms are bridged by water molecu...

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Main Authors: Lian-Sheng Yu, Jing-Quan Sha, Li-Xin Liu, Hai-Yan Liu
Format: Article
Language:English
Published: International Union of Crystallography 2010-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810037384
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spelling doaj-8607e31f651342fc899b269c9c36955e2020-11-24T21:22:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610m1336m133710.1107/S1600536810037384catena-Poly[[(5-carboxy-2H-1,2,3-triazole-4-carboxylato-κ2N3,O4)sodium]-di-μ-aqua-κ4O:O]Lian-Sheng YuJing-Quan ShaLi-Xin LiuHai-Yan LiuIn the title coordination polymer, [Na(C4H2N3O4)(H2O)2]n, the NaI atom is six-coordinated by one O atom and one N atom from a 2H-1,2,3-triazole-4-carboxy-5-carboxylate ligand and four O atoms from four water molecules, forming a distorted octahedal geometry. The NaI atoms are bridged by water molecules into a chain structure along [100]. Intermolecular N—H...O, O—H...N and O—H...O hydrogen bonds connect the chains. An intramolecular O—H...O hydrogen bond between the carboxylate groups is observed. http://scripts.iucr.org/cgi-bin/paper?S1600536810037384
collection DOAJ
language English
format Article
sources DOAJ
author Lian-Sheng Yu
Jing-Quan Sha
Li-Xin Liu
Hai-Yan Liu
spellingShingle Lian-Sheng Yu
Jing-Quan Sha
Li-Xin Liu
Hai-Yan Liu
catena-Poly[[(5-carboxy-2H-1,2,3-triazole-4-carboxylato-κ2N3,O4)sodium]-di-μ-aqua-κ4O:O]
Acta Crystallographica Section E
author_facet Lian-Sheng Yu
Jing-Quan Sha
Li-Xin Liu
Hai-Yan Liu
author_sort Lian-Sheng Yu
title catena-Poly[[(5-carboxy-2H-1,2,3-triazole-4-carboxylato-κ2N3,O4)sodium]-di-μ-aqua-κ4O:O]
title_short catena-Poly[[(5-carboxy-2H-1,2,3-triazole-4-carboxylato-κ2N3,O4)sodium]-di-μ-aqua-κ4O:O]
title_full catena-Poly[[(5-carboxy-2H-1,2,3-triazole-4-carboxylato-κ2N3,O4)sodium]-di-μ-aqua-κ4O:O]
title_fullStr catena-Poly[[(5-carboxy-2H-1,2,3-triazole-4-carboxylato-κ2N3,O4)sodium]-di-μ-aqua-κ4O:O]
title_full_unstemmed catena-Poly[[(5-carboxy-2H-1,2,3-triazole-4-carboxylato-κ2N3,O4)sodium]-di-μ-aqua-κ4O:O]
title_sort catena-poly[[(5-carboxy-2h-1,2,3-triazole-4-carboxylato-κ2n3,o4)sodium]-di-μ-aqua-κ4o:o]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-10-01
description In the title coordination polymer, [Na(C4H2N3O4)(H2O)2]n, the NaI atom is six-coordinated by one O atom and one N atom from a 2H-1,2,3-triazole-4-carboxy-5-carboxylate ligand and four O atoms from four water molecules, forming a distorted octahedal geometry. The NaI atoms are bridged by water molecules into a chain structure along [100]. Intermolecular N—H...O, O—H...N and O—H...O hydrogen bonds connect the chains. An intramolecular O—H...O hydrogen bond between the carboxylate groups is observed.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810037384
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