catena-Poly[(E)-4,4′-(ethane-1,2-diyl)dipyridinium [[bis(thiocyanato-κN)ferrate(II)]-di-μ-thiocyanato-κ2N:S;κ2S:N]]

catena-Poly[(E)-4,4′-(ethane-1,2-diyl)dipyridinium [[bis(thiocyanato-κN)ferrate(II)]-di-μ-thiocyanato-κ2N:S;κ2S:N]]

In the crystal structure of the title compound, {(C12H14N2)[Fe(NCS)4]}n, the iron(II) cation is coordinated by four N-bonded and two S-bonded thiocyanate anions in a distorted octahedral coordination mode. The asymmetric unit consists of half an iron(II) cation and half a protonated (E)-4,4&...

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Main Authors: Susanne Wöhlert, Inke Jess, Christian Näther
Format: Article
Language:English
Published: International Union of Crystallography 2011-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811039924
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spelling doaj-85d616ef9aaf441f99222fb11513002c2020-11-24T22:15:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-11-016711m1503m150310.1107/S1600536811039924catena-Poly[(E)-4,4′-(ethane-1,2-diyl)dipyridinium [[bis(thiocyanato-κN)ferrate(II)]-di-μ-thiocyanato-κ2N:S;κ2S:N]]Susanne WöhlertInke JessChristian NätherIn the crystal structure of the title compound, {(C12H14N2)[Fe(NCS)4]}n, the iron(II) cation is coordinated by four N-bonded and two S-bonded thiocyanate anions in a distorted octahedral coordination mode. The asymmetric unit consists of half an iron(II) cation and half a protonated (E)-4,4′-(ethane-1,2-diyl)dipyridinium dication, each located on a centre of inversion. In addition, there are two thiocyanate anions in general positions. The crystal structure consists of Fe—(NCS)2—Fe chains in which each iron(II) cation is additionally coordinated by two terminal N-bonded thiocyanate anions. Non-coordinating dipyridinium dications are present between the thiocyanatoferrate(II) chains and are connected to the anions via N—H...N and N—H...S hydrogen-bond interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536811039924
collection DOAJ
language English
format Article
sources DOAJ
author Susanne Wöhlert
Inke Jess
Christian Näther
spellingShingle Susanne Wöhlert
Inke Jess
Christian Näther
catena-Poly[(E)-4,4′-(ethane-1,2-diyl)dipyridinium [[bis(thiocyanato-κN)ferrate(II)]-di-μ-thiocyanato-κ2N:S;κ2S:N]]
Acta Crystallographica Section E
author_facet Susanne Wöhlert
Inke Jess
Christian Näther
author_sort Susanne Wöhlert
title catena-Poly[(E)-4,4′-(ethane-1,2-diyl)dipyridinium [[bis(thiocyanato-κN)ferrate(II)]-di-μ-thiocyanato-κ2N:S;κ2S:N]]
title_short catena-Poly[(E)-4,4′-(ethane-1,2-diyl)dipyridinium [[bis(thiocyanato-κN)ferrate(II)]-di-μ-thiocyanato-κ2N:S;κ2S:N]]
title_full catena-Poly[(E)-4,4′-(ethane-1,2-diyl)dipyridinium [[bis(thiocyanato-κN)ferrate(II)]-di-μ-thiocyanato-κ2N:S;κ2S:N]]
title_fullStr catena-Poly[(E)-4,4′-(ethane-1,2-diyl)dipyridinium [[bis(thiocyanato-κN)ferrate(II)]-di-μ-thiocyanato-κ2N:S;κ2S:N]]
title_full_unstemmed catena-Poly[(E)-4,4′-(ethane-1,2-diyl)dipyridinium [[bis(thiocyanato-κN)ferrate(II)]-di-μ-thiocyanato-κ2N:S;κ2S:N]]
title_sort catena-poly[(e)-4,4′-(ethane-1,2-diyl)dipyridinium [[bis(thiocyanato-κn)ferrate(ii)]-di-μ-thiocyanato-κ2n:s;κ2s:n]]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-11-01
description In the crystal structure of the title compound, {(C12H14N2)[Fe(NCS)4]}n, the iron(II) cation is coordinated by four N-bonded and two S-bonded thiocyanate anions in a distorted octahedral coordination mode. The asymmetric unit consists of half an iron(II) cation and half a protonated (E)-4,4′-(ethane-1,2-diyl)dipyridinium dication, each located on a centre of inversion. In addition, there are two thiocyanate anions in general positions. The crystal structure consists of Fe—(NCS)2—Fe chains in which each iron(II) cation is additionally coordinated by two terminal N-bonded thiocyanate anions. Non-coordinating dipyridinium dications are present between the thiocyanatoferrate(II) chains and are connected to the anions via N—H...N and N—H...S hydrogen-bond interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811039924
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AT inkejess catenapolye44amp8242ethane12diyldipyridiniumbisthiocyanatoamp954nferrateiidiamp956thiocyanatoamp9542nsamp9542sn
AT christiannamp228ther catenapolye44amp8242ethane12diyldipyridiniumbisthiocyanatoamp954nferrateiidiamp956thiocyanatoamp9542nsamp9542sn
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