Direct C(sp2)–H alkylation of unactivated arenes enabled by photoinduced Pd catalysis

Direct C(sp2)–H alkylation of unactivated arenes enabled by photoinduced Pd catalysis

Direct catalytic C(sp2)–H alkylation of unactivated arenes with alkyl halides remains elusive despite the progress in C-H functionalization. Here, the authors report the catalytic C(sp2)–H alkylation of unactivated arenes with alkyl bromides via visible-light induced Pd catalysis.

Bibliographic Details
Main Authors: Daeun Kim, Geun Seok Lee, Dongwook Kim, Soon Hyeok Hong
Format: Article
Language:English
Published: Nature Publishing Group 2020-10-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-020-19038-8
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spelling doaj-858dc7b0696a4b23b2eb53c2c3f231a82021-05-11T08:35:18ZengNature Publishing GroupNature Communications2041-17232020-10-0111111310.1038/s41467-020-19038-8Direct C(sp2)–H alkylation of unactivated arenes enabled by photoinduced Pd catalysisDaeun Kim0Geun Seok Lee1Dongwook Kim2Soon Hyeok Hong3Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST)Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST)Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST)Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST)Direct catalytic C(sp2)–H alkylation of unactivated arenes with alkyl halides remains elusive despite the progress in C-H functionalization. Here, the authors report the catalytic C(sp2)–H alkylation of unactivated arenes with alkyl bromides via visible-light induced Pd catalysis.https://doi.org/10.1038/s41467-020-19038-8
collection DOAJ
language English
format Article
sources DOAJ
author Daeun Kim
Geun Seok Lee
Dongwook Kim
Soon Hyeok Hong
spellingShingle Daeun Kim
Geun Seok Lee
Dongwook Kim
Soon Hyeok Hong
Direct C(sp2)–H alkylation of unactivated arenes enabled by photoinduced Pd catalysis
Nature Communications
author_facet Daeun Kim
Geun Seok Lee
Dongwook Kim
Soon Hyeok Hong
author_sort Daeun Kim
title Direct C(sp2)–H alkylation of unactivated arenes enabled by photoinduced Pd catalysis
title_short Direct C(sp2)–H alkylation of unactivated arenes enabled by photoinduced Pd catalysis
title_full Direct C(sp2)–H alkylation of unactivated arenes enabled by photoinduced Pd catalysis
title_fullStr Direct C(sp2)–H alkylation of unactivated arenes enabled by photoinduced Pd catalysis
title_full_unstemmed Direct C(sp2)–H alkylation of unactivated arenes enabled by photoinduced Pd catalysis
title_sort direct c(sp2)–h alkylation of unactivated arenes enabled by photoinduced pd catalysis
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2020-10-01
description Direct catalytic C(sp2)–H alkylation of unactivated arenes with alkyl halides remains elusive despite the progress in C-H functionalization. Here, the authors report the catalytic C(sp2)–H alkylation of unactivated arenes with alkyl bromides via visible-light induced Pd catalysis.
url https://doi.org/10.1038/s41467-020-19038-8
work_keys_str_mv AT daeunkim directcsp2halkylationofunactivatedarenesenabledbyphotoinducedpdcatalysis
AT geunseoklee directcsp2halkylationofunactivatedarenesenabledbyphotoinducedpdcatalysis
AT dongwookkim directcsp2halkylationofunactivatedarenesenabledbyphotoinducedpdcatalysis
AT soonhyeokhong directcsp2halkylationofunactivatedarenesenabledbyphotoinducedpdcatalysis
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