Bis[4-amino-N-(4-methylpyrimidin-2-yl-κN3)benzenesulfonamidato-κN](2,2′-bipyridine-κ2N,N′)mercury(II)
The complete molecule of the title complex, [Hg(C11H11N4O2S)2(C10H8N2)], is generated by crystallographic twofold symmetry, with the mercury cation lying on the rotation axis. The mercury coordination polyhedron can be described as tetrahedral (from the N,N′-bidenate bipyridine molecule and the sulf...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2014-04-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814004760 |
| id |
doaj-85677eb8b74842dda2af68d3c6ab706e |
|---|---|
| record_format |
Article |
| spelling |
doaj-85677eb8b74842dda2af68d3c6ab706e2020-11-24T22:10:08ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-04-01704m127m12810.1107/S1600536814004760hb7201Bis[4-amino-N-(4-methylpyrimidin-2-yl-κN3)benzenesulfonamidato-κN](2,2′-bipyridine-κ2N,N′)mercury(II)G. M. Golzar Hossain0A. J. Amoroso1Department of Chemistry, University of Dhaka, Dhaka 1000, BangladeshSchool of Chemistry, Cardiff University, Cardiff CF10 3AT, WalesThe complete molecule of the title complex, [Hg(C11H11N4O2S)2(C10H8N2)], is generated by crystallographic twofold symmetry, with the mercury cation lying on the rotation axis. The mercury coordination polyhedron can be described as tetrahedral (from the N,N′-bidenate bipyridine molecule and the sulfonamide N atoms of the sulfamerazine anions) or as squashed trigonal-prismatic, if two long (> 2.80 Å) Hg—N bonds to pyrimidine N atoms are included. The dihedral angle between the aromatic rings in the anion is 73.3 (2)°. In the crystal, N—H...(N,O) and N—H...N hydrogen bonds link the molecules into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536814004760 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
G. M. Golzar Hossain A. J. Amoroso |
| spellingShingle |
G. M. Golzar Hossain A. J. Amoroso Bis[4-amino-N-(4-methylpyrimidin-2-yl-κN3)benzenesulfonamidato-κN](2,2′-bipyridine-κ2N,N′)mercury(II) Acta Crystallographica Section E |
| author_facet |
G. M. Golzar Hossain A. J. Amoroso |
| author_sort |
G. M. Golzar Hossain |
| title |
Bis[4-amino-N-(4-methylpyrimidin-2-yl-κN3)benzenesulfonamidato-κN](2,2′-bipyridine-κ2N,N′)mercury(II) |
| title_short |
Bis[4-amino-N-(4-methylpyrimidin-2-yl-κN3)benzenesulfonamidato-κN](2,2′-bipyridine-κ2N,N′)mercury(II) |
| title_full |
Bis[4-amino-N-(4-methylpyrimidin-2-yl-κN3)benzenesulfonamidato-κN](2,2′-bipyridine-κ2N,N′)mercury(II) |
| title_fullStr |
Bis[4-amino-N-(4-methylpyrimidin-2-yl-κN3)benzenesulfonamidato-κN](2,2′-bipyridine-κ2N,N′)mercury(II) |
| title_full_unstemmed |
Bis[4-amino-N-(4-methylpyrimidin-2-yl-κN3)benzenesulfonamidato-κN](2,2′-bipyridine-κ2N,N′)mercury(II) |
| title_sort |
bis[4-amino-n-(4-methylpyrimidin-2-yl-κn3)benzenesulfonamidato-κn](2,2′-bipyridine-κ2n,n′)mercury(ii) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2014-04-01 |
| description |
The complete molecule of the title complex, [Hg(C11H11N4O2S)2(C10H8N2)], is generated by crystallographic twofold symmetry, with the mercury cation lying on the rotation axis. The mercury coordination polyhedron can be described as tetrahedral (from the N,N′-bidenate bipyridine molecule and the sulfonamide N atoms of the sulfamerazine anions) or as squashed trigonal-prismatic, if two long (> 2.80 Å) Hg—N bonds to pyrimidine N atoms are included. The dihedral angle between the aromatic rings in the anion is 73.3 (2)°. In the crystal, N—H...(N,O) and N—H...N hydrogen bonds link the molecules into a three-dimensional network. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536814004760 |
| work_keys_str_mv |
AT gmgolzarhossain bis4aminon4methylpyrimidin2ylkn3benzenesulfonamidatokn22bipyridinek2nnmercuryii AT ajamoroso bis4aminon4methylpyrimidin2ylkn3benzenesulfonamidatokn22bipyridinek2nnmercuryii |
| _version_ |
1725809042490654720 |