Tetrapotassium cis-dioxido-trans-bis(sulfato-κO)sulfato(κ2O,O′)molybdate(VI)

Tetrapotassium cis-dioxido-trans-bis(sulfato-κO)sulfato(κ2O,O′)molybdate(VI)

The title compound, K4[MoVIO2(SO4)3], was precipitated from a melt of molybdenum(VI) oxide and potassium sulfate in potassium disulfate. The compound contains monomeric [MoVIO2(SO4)3]4− anions, with the MoVI atom, both oxide ligands, and the S atom and both ligating O atoms of the bidentat...

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Main Authors: Rolf W. Berg, Susan J. Cline Schäffer
Format: Article
Language:English
Published: International Union of Crystallography 2008-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808003851
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spelling doaj-84fd626190b6446a803200c896c364102020-11-25T00:46:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-03-01643i20i2010.1107/S1600536808003851Tetrapotassium cis-dioxido-trans-bis(sulfato-κO)sulfato(κ2O,O′)molybdate(VI)Rolf W. BergSusan J. Cline SchäfferThe title compound, K4[MoVIO2(SO4)3], was precipitated from a melt of molybdenum(VI) oxide and potassium sulfate in potassium disulfate. The compound contains monomeric [MoVIO2(SO4)3]4− anions, with the MoVI atom, both oxide ligands, and the S atom and both ligating O atoms of the bidentate sulfate group lying on a crystallographic mirror plane. One of the potassium cations is nine-coordinate, while the other is eight-coordinate.http://scripts.iucr.org/cgi-bin/paper?S1600536808003851
collection DOAJ
language English
format Article
sources DOAJ
author Rolf W. Berg
Susan J. Cline Schäffer
spellingShingle Rolf W. Berg
Susan J. Cline Schäffer
Tetrapotassium cis-dioxido-trans-bis(sulfato-κO)sulfato(κ2O,O′)molybdate(VI)
Acta Crystallographica Section E
author_facet Rolf W. Berg
Susan J. Cline Schäffer
author_sort Rolf W. Berg
title Tetrapotassium cis-dioxido-trans-bis(sulfato-κO)sulfato(κ2O,O′)molybdate(VI)
title_short Tetrapotassium cis-dioxido-trans-bis(sulfato-κO)sulfato(κ2O,O′)molybdate(VI)
title_full Tetrapotassium cis-dioxido-trans-bis(sulfato-κO)sulfato(κ2O,O′)molybdate(VI)
title_fullStr Tetrapotassium cis-dioxido-trans-bis(sulfato-κO)sulfato(κ2O,O′)molybdate(VI)
title_full_unstemmed Tetrapotassium cis-dioxido-trans-bis(sulfato-κO)sulfato(κ2O,O′)molybdate(VI)
title_sort tetrapotassium cis-dioxido-trans-bis(sulfato-κo)sulfato(κ2o,o′)molybdate(vi)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-03-01
description The title compound, K4[MoVIO2(SO4)3], was precipitated from a melt of molybdenum(VI) oxide and potassium sulfate in potassium disulfate. The compound contains monomeric [MoVIO2(SO4)3]4− anions, with the MoVI atom, both oxide ligands, and the S atom and both ligating O atoms of the bidentate sulfate group lying on a crystallographic mirror plane. One of the potassium cations is nine-coordinate, while the other is eight-coordinate.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808003851
work_keys_str_mv AT rolfwberg tetrapotassiumcisdioxidotransbissulfato954osulfato9542oo8242molybdatevi
AT susanjclinesch228ffer tetrapotassiumcisdioxidotransbissulfato954osulfato9542oo8242molybdatevi
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