Poly[[diaqua(3-carboxy-5-nitrobenzoato)(μ-5-nitrobenzene-1,3-dicarboxylato)neodymium(III)] 2.5-hydrate]

Poly[[diaqua(3-carboxy-5-nitrobenzoato)(μ-5-nitrobenzene-1,3-dicarboxylato)neodymium(III)] 2.5-hydrate]

In the title compound, {[Nd(C8H3NO6)(C8H4NO6)(H2O)2]·2.5H2O}n, the NdII ion is nine-coordinated by seven O atoms from five carboxylate groups and two water molecules. The [Nd(C8H3NO6)(H2O)2]2+ units are bridged by 5-nitroisophthalate dianions, forming polymeric sheets parallel to the ab...

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Main Authors: Nurul-Nadia Raime, Rohana Adnan, Mohd Mustaqim Rosli, Hoong-Kun Fun
Format: Article
Language:English
Published: International Union of Crystallography 2009-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809032486
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spelling doaj-8479277b780049fb80ec0d3e42d30fbb2020-11-24T21:30:48ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-09-01659m1108m110910.1107/S1600536809032486Poly[[diaqua(3-carboxy-5-nitrobenzoato)(μ-5-nitrobenzene-1,3-dicarboxylato)neodymium(III)] 2.5-hydrate]Nurul-Nadia RaimeRohana AdnanMohd Mustaqim RosliHoong-Kun FunIn the title compound, {[Nd(C8H3NO6)(C8H4NO6)(H2O)2]·2.5H2O}n, the NdII ion is nine-coordinated by seven O atoms from five carboxylate groups and two water molecules. The [Nd(C8H3NO6)(H2O)2]2+ units are bridged by 5-nitroisophthalate dianions, forming polymeric sheets parallel to the ab plane. The polymeric sheets are linked into a three-dimensional network by O—H...O and C—H...O hydrogen bonds, and π–π interactions [centroid–centroid distance = 3.5533 (11) Å]. The 5-nitroisophthalate(1−) anion is disordered over three positions with an occupancy ratio of 0.68:0.23:0.09. Two of the uncoordinated water molecules are disordered over two positions, with occupancy ratios of 0.722 (15):0.278 (15) and 0.279 (6):0.221 (6), respectively. http://scripts.iucr.org/cgi-bin/paper?S1600536809032486
collection DOAJ
language English
format Article
sources DOAJ
author Nurul-Nadia Raime
Rohana Adnan
Mohd Mustaqim Rosli
Hoong-Kun Fun
spellingShingle Nurul-Nadia Raime
Rohana Adnan
Mohd Mustaqim Rosli
Hoong-Kun Fun
Poly[[diaqua(3-carboxy-5-nitrobenzoato)(μ-5-nitrobenzene-1,3-dicarboxylato)neodymium(III)] 2.5-hydrate]
Acta Crystallographica Section E
author_facet Nurul-Nadia Raime
Rohana Adnan
Mohd Mustaqim Rosli
Hoong-Kun Fun
author_sort Nurul-Nadia Raime
title Poly[[diaqua(3-carboxy-5-nitrobenzoato)(μ-5-nitrobenzene-1,3-dicarboxylato)neodymium(III)] 2.5-hydrate]
title_short Poly[[diaqua(3-carboxy-5-nitrobenzoato)(μ-5-nitrobenzene-1,3-dicarboxylato)neodymium(III)] 2.5-hydrate]
title_full Poly[[diaqua(3-carboxy-5-nitrobenzoato)(μ-5-nitrobenzene-1,3-dicarboxylato)neodymium(III)] 2.5-hydrate]
title_fullStr Poly[[diaqua(3-carboxy-5-nitrobenzoato)(μ-5-nitrobenzene-1,3-dicarboxylato)neodymium(III)] 2.5-hydrate]
title_full_unstemmed Poly[[diaqua(3-carboxy-5-nitrobenzoato)(μ-5-nitrobenzene-1,3-dicarboxylato)neodymium(III)] 2.5-hydrate]
title_sort poly[[diaqua(3-carboxy-5-nitrobenzoato)(μ-5-nitrobenzene-1,3-dicarboxylato)neodymium(iii)] 2.5-hydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-09-01
description In the title compound, {[Nd(C8H3NO6)(C8H4NO6)(H2O)2]·2.5H2O}n, the NdII ion is nine-coordinated by seven O atoms from five carboxylate groups and two water molecules. The [Nd(C8H3NO6)(H2O)2]2+ units are bridged by 5-nitroisophthalate dianions, forming polymeric sheets parallel to the ab plane. The polymeric sheets are linked into a three-dimensional network by O—H...O and C—H...O hydrogen bonds, and π–π interactions [centroid–centroid distance = 3.5533 (11) Å]. The 5-nitroisophthalate(1−) anion is disordered over three positions with an occupancy ratio of 0.68:0.23:0.09. Two of the uncoordinated water molecules are disordered over two positions, with occupancy ratios of 0.722 (15):0.278 (15) and 0.279 (6):0.221 (6), respectively.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809032486
work_keys_str_mv AT nurulnadiaraime polydiaqua3carboxy5nitrobenzoatoamp9565nitrobenzene13dicarboxylatoneodymiumiii25hydrate
AT rohanaadnan polydiaqua3carboxy5nitrobenzoatoamp9565nitrobenzene13dicarboxylatoneodymiumiii25hydrate
AT mohdmustaqimrosli polydiaqua3carboxy5nitrobenzoatoamp9565nitrobenzene13dicarboxylatoneodymiumiii25hydrate
AT hoongkunfun polydiaqua3carboxy5nitrobenzoatoamp9565nitrobenzene13dicarboxylatoneodymiumiii25hydrate
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