Electrochemical Hydrogen Production Using Separated-Gas Cells for Soybean Oil Hydrogenation

Although hydrogen is the most abundant element in the universe, it is not possible to find it in its purest state in nature. In this study, two-stage experimentation was carried out. The first stage was hydrogen production. The second stage was an electrochemical process to hydrogenate soybean oil i...

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Bibliographic Details
Main Authors: Jorge Eduardo Esquerre Verastegui, Marco Antonio Zamora Antuñano, Juvenal Rodríguez Resendiz, Raul García García, Pedro Jacinto Paramo Kañetas, Daniel Larrañaga Ordaz
Format: Article
Language:English
Published: MDPI AG 2020-07-01
Series:Processes
Subjects:
Online Access:https://www.mdpi.com/2227-9717/8/7/832
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Summary:Although hydrogen is the most abundant element in the universe, it is not possible to find it in its purest state in nature. In this study, two-stage experimentation was carried out. The first stage was hydrogen production. The second stage was an electrochemical process to hydrogenate soybean oil in a PEM fuel cell. In the fist stage a Zirfon Perl UTP 500 membrane was used in an alkaline hydrolizer of separated gas to produce hydrogen, achieving 9.6 L/min compared with 5.1 L/min, the maximum obtained using a conventional membrane. The hydrogen obtained was used in the second stage to feed the fuel cell hydrogenating the soybean oil. Hydrogenated soybean oil showed a substantial diminished iodine index from 131 to 54.85, which represents a percentage of 58.13. This happens when applying a voltage of 90 mV for 240 min, constant temperature of 50 <inline-formula> <math display="inline"> <semantics> <msup> <mrow></mrow> <mo>∘</mo> </msup> </semantics> </math> </inline-formula>C and one atm. This result was obtained by depositing 1 mg of Pt/cm<inline-formula> <math display="inline"> <semantics> <msup> <mrow></mrow> <mn>2</mn> </msup> </semantics> </math> </inline-formula> in the cathode of the fuel cell. This system represents a viable alternative for the use of hydrogen in energy generation.
ISSN:2227-9717