A Zn(II) Metallocycle as Platform to Assemble a 1D + 1D → 1D Polyrotaxane via π···π Stacking of an Ancillary Ligand

A Zn(II) Metallocycle as Platform to Assemble a 1D + 1D → 1D Polyrotaxane via π···π Stacking of an Ancillary Ligand

A new [Zn<sub>2</sub>L<sub>2</sub>] metallocycle bearing two metal centers that can coordinate ancillary ligands and a pocket suitable to host guest molecules is reported. These two features are exploited by reacting the metallocycle with a pyridine ligand to self-assemble in...

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Bibliographic Details
Main Authors: Marzio Rancan, Giada Truccolo, Alice Carlotto, Silvio Quici, Lidia Armelao
Format: Article
Language:English
Published: MDPI AG 2019-11-01
Series:Inorganics
Subjects:
polyrotaxane
metallocycle
metalloring
self-assembly
pi stacking
zinc
ancillary ligand
Online Access:https://www.mdpi.com/2304-6740/7/11/137

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