Study of the Potential of Water Treatment Sludges in the Removal of Emerging Pollutants

Presently, water quantity and quality problems persist both in developed and developing countries, and concerns have been raised about the presence of emerging pollutants (EPs) in water. The circular economy provides ways of achieving sustainable resource management that can be implemented in the wa...

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Main Authors: Rita Dias, Diogo Sousa, Maria Bernardo, Inês Matos, Isabel Fonseca, Vitor Vale Cardoso, Rui Neves Carneiro, Sofia Silva, Pedro Fontes, Michiel A. Daam, Rita Maurício
Format: Article
Language:English
Published: MDPI AG 2021-02-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/26/4/1010
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spelling doaj-81e9eada2e0d4be2ba7b60cd122e28ba2021-02-15T00:02:19ZengMDPI AGMolecules1420-30492021-02-01261010101010.3390/molecules26041010Study of the Potential of Water Treatment Sludges in the Removal of Emerging PollutantsRita Dias0Diogo Sousa1Maria Bernardo2Inês Matos3Isabel Fonseca4Vitor Vale Cardoso5Rui Neves Carneiro6Sofia Silva7Pedro Fontes8Michiel A. Daam9Rita Maurício10CENSE—Center for Environmental and Sustainability Research, School of Science and Technology, NOVA University Lisbon, 2829-516 Caparica, PortugalCENSE—Center for Environmental and Sustainability Research, School of Science and Technology, NOVA University Lisbon, 2829-516 Caparica, PortugalLAQV/REQUIMTE, School of Science and Technology, NOVA University Lisbon, 2829-516 Caparica, PortugalLAQV/REQUIMTE, School of Science and Technology, NOVA University Lisbon, 2829-516 Caparica, PortugalLAQV/REQUIMTE, School of Science and Technology, NOVA University Lisbon, 2829-516 Caparica, PortugalEPAL—Empresa Pública de Águas Lives S.A.,-AdP—Grupo Águas de Portugal, 31700-421 Lisboa, PortugalEPAL—Empresa Pública de Águas Lives S.A.,-AdP—Grupo Águas de Portugal, 31700-421 Lisboa, PortugalEPAL—Empresa Pública de Águas Lives S.A.,-AdP—Grupo Águas de Portugal, 31700-421 Lisboa, PortugalEPAL—Empresa Pública de Águas Lives S.A.,-AdP—Grupo Águas de Portugal, 31700-421 Lisboa, PortugalCENSE—Center for Environmental and Sustainability Research, School of Science and Technology, NOVA University Lisbon, 2829-516 Caparica, PortugalCENSE—Center for Environmental and Sustainability Research, School of Science and Technology, NOVA University Lisbon, 2829-516 Caparica, PortugalPresently, water quantity and quality problems persist both in developed and developing countries, and concerns have been raised about the presence of emerging pollutants (EPs) in water. The circular economy provides ways of achieving sustainable resource management that can be implemented in the water sector, such as the reuse of drinking water treatment sludges (WTSs). This study evaluated the potential of WTS containing a high concentration of activated carbon for the removal of two EPs: the steroid hormones 17β-estradiol (E2) and 17α-ethinylestradiol (EE2). To this end, WTSs from two Portuguese water treatment plants (WTPs) were characterised and tested for their hormone adsorbance potential. Both WTSs showed a promising adsorption potential for the two hormones studied due to their textural and chemical properties. For WTS1, the final concentration for both hormones was lower than the limit of quantification (LOQ). As for WTS2, the results for E2 removal were similar to WTS1, although for EE2, the removal efficiency was lower (around 50%). The overall results indicate that this method may lead to new ways of using this erstwhile residue as a possible adsorbent material for the removal of several EPs present in wastewaters or other matrixes, and as such contributing to the achievement of Sustainable Development Goals (SDG) targets.https://www.mdpi.com/1420-3049/26/4/1010emerging pollutantswater treatment sludgesadsorption processescircular economy
collection DOAJ
language English
format Article
sources DOAJ
author Rita Dias
Diogo Sousa
Maria Bernardo
Inês Matos
Isabel Fonseca
Vitor Vale Cardoso
Rui Neves Carneiro
Sofia Silva
Pedro Fontes
Michiel A. Daam
Rita Maurício
spellingShingle Rita Dias
Diogo Sousa
Maria Bernardo
Inês Matos
Isabel Fonseca
Vitor Vale Cardoso
Rui Neves Carneiro
Sofia Silva
Pedro Fontes
Michiel A. Daam
Rita Maurício
Study of the Potential of Water Treatment Sludges in the Removal of Emerging Pollutants
Molecules
emerging pollutants
water treatment sludges
adsorption processes
circular economy
author_facet Rita Dias
Diogo Sousa
Maria Bernardo
Inês Matos
Isabel Fonseca
Vitor Vale Cardoso
Rui Neves Carneiro
Sofia Silva
Pedro Fontes
Michiel A. Daam
Rita Maurício
author_sort Rita Dias
title Study of the Potential of Water Treatment Sludges in the Removal of Emerging Pollutants
title_short Study of the Potential of Water Treatment Sludges in the Removal of Emerging Pollutants
title_full Study of the Potential of Water Treatment Sludges in the Removal of Emerging Pollutants
title_fullStr Study of the Potential of Water Treatment Sludges in the Removal of Emerging Pollutants
title_full_unstemmed Study of the Potential of Water Treatment Sludges in the Removal of Emerging Pollutants
title_sort study of the potential of water treatment sludges in the removal of emerging pollutants
publisher MDPI AG
series Molecules
issn 1420-3049
publishDate 2021-02-01
description Presently, water quantity and quality problems persist both in developed and developing countries, and concerns have been raised about the presence of emerging pollutants (EPs) in water. The circular economy provides ways of achieving sustainable resource management that can be implemented in the water sector, such as the reuse of drinking water treatment sludges (WTSs). This study evaluated the potential of WTS containing a high concentration of activated carbon for the removal of two EPs: the steroid hormones 17β-estradiol (E2) and 17α-ethinylestradiol (EE2). To this end, WTSs from two Portuguese water treatment plants (WTPs) were characterised and tested for their hormone adsorbance potential. Both WTSs showed a promising adsorption potential for the two hormones studied due to their textural and chemical properties. For WTS1, the final concentration for both hormones was lower than the limit of quantification (LOQ). As for WTS2, the results for E2 removal were similar to WTS1, although for EE2, the removal efficiency was lower (around 50%). The overall results indicate that this method may lead to new ways of using this erstwhile residue as a possible adsorbent material for the removal of several EPs present in wastewaters or other matrixes, and as such contributing to the achievement of Sustainable Development Goals (SDG) targets.
topic emerging pollutants
water treatment sludges
adsorption processes
circular economy
url https://www.mdpi.com/1420-3049/26/4/1010
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