catena-Poly[aquabis(μ-3-chlorobenzoato-κ2O:O′)zinc]

catena-Poly[aquabis(μ-3-chlorobenzoato-κ2O:O′)zinc]

In the polymeric title compound, [Zn(C7H4ClO2)2(H2O)]n, the ZnII cation is located on a twofold rotation axis and is coordinated by carboxylate O atoms of four monodentate chlorobenzoate anions and by one water molecule, located on a twofold rotation axis, in a distorted square-pyramidal geometry. I...

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Main Authors: Nihat Bozkurt, Nefise Dilek, Nagihan Çaylak Delibaş, Hacali Necefoğlu, Tuncer Hökelek
Format: Article
Language:English
Published: International Union of Crystallography 2013-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681301564X
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spelling doaj-805925ad250747a7a5d9479d5f25654a2020-11-25T01:35:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-07-01697m381m38210.1107/S160053681301564Xcatena-Poly[aquabis(μ-3-chlorobenzoato-κ2O:O′)zinc]Nihat BozkurtNefise DilekNagihan Çaylak DelibaşHacali NecefoğluTuncer HökelekIn the polymeric title compound, [Zn(C7H4ClO2)2(H2O)]n, the ZnII cation is located on a twofold rotation axis and is coordinated by carboxylate O atoms of four monodentate chlorobenzoate anions and by one water molecule, located on a twofold rotation axis, in a distorted square-pyramidal geometry. In the anion, the carboxylate group is twisted away from the attached benzene ring by 44.16 (11)°. The chlorobenzoate anion bridges ZnII cations, forming polymeric chains running along the c-axis direction. O—H...O hydrogen bonds between coordinating water molecules and carboxylate groups link adjacent chains into layers parallel to the bc plane.http://scripts.iucr.org/cgi-bin/paper?S160053681301564X
collection DOAJ
language English
format Article
sources DOAJ
author Nihat Bozkurt
Nefise Dilek
Nagihan Çaylak Delibaş
Hacali Necefoğlu
Tuncer Hökelek
spellingShingle Nihat Bozkurt
Nefise Dilek
Nagihan Çaylak Delibaş
Hacali Necefoğlu
Tuncer Hökelek
catena-Poly[aquabis(μ-3-chlorobenzoato-κ2O:O′)zinc]
Acta Crystallographica Section E
author_facet Nihat Bozkurt
Nefise Dilek
Nagihan Çaylak Delibaş
Hacali Necefoğlu
Tuncer Hökelek
author_sort Nihat Bozkurt
title catena-Poly[aquabis(μ-3-chlorobenzoato-κ2O:O′)zinc]
title_short catena-Poly[aquabis(μ-3-chlorobenzoato-κ2O:O′)zinc]
title_full catena-Poly[aquabis(μ-3-chlorobenzoato-κ2O:O′)zinc]
title_fullStr catena-Poly[aquabis(μ-3-chlorobenzoato-κ2O:O′)zinc]
title_full_unstemmed catena-Poly[aquabis(μ-3-chlorobenzoato-κ2O:O′)zinc]
title_sort catena-poly[aquabis(μ-3-chlorobenzoato-κ2o:o′)zinc]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-07-01
description In the polymeric title compound, [Zn(C7H4ClO2)2(H2O)]n, the ZnII cation is located on a twofold rotation axis and is coordinated by carboxylate O atoms of four monodentate chlorobenzoate anions and by one water molecule, located on a twofold rotation axis, in a distorted square-pyramidal geometry. In the anion, the carboxylate group is twisted away from the attached benzene ring by 44.16 (11)°. The chlorobenzoate anion bridges ZnII cations, forming polymeric chains running along the c-axis direction. O—H...O hydrogen bonds between coordinating water molecules and carboxylate groups link adjacent chains into layers parallel to the bc plane.
url http://scripts.iucr.org/cgi-bin/paper?S160053681301564X
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AT nefisedilek catenapolyaquabis9563chlorobenzoato9542oo8242zinc
AT nagihan199aylakdeliba351 catenapolyaquabis9563chlorobenzoato9542oo8242zinc
AT hacalinecefo287lu catenapolyaquabis9563chlorobenzoato9542oo8242zinc
AT tuncerh246kelek catenapolyaquabis9563chlorobenzoato9542oo8242zinc
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