Activation of the Cyano Group at Imidazole via Copper Stimulated Alcoholysis

Activation of the Cyano Group at Imidazole via Copper Stimulated Alcoholysis

Reactions of 4,5-dicyano-1-methylimidazole with CuX<sub>2</sub> (X = Cl, Br) in alcohol solvents (ethanol and methanol) resulted in the formation of Cu(II) carboximidate complexes [CuCl<sub>2</sub>(5- cyano-4-C(OEt)N-1-methylimidazole)(EtOH)] (<b>1</b>), [Cu<su...

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Bibliographic Details
Main Authors: Rezeda Gayfullina, Sirpa Jääskeläinen, Igor O. Koshevoy, Pipsa Hirva
Format: Article
Language:English
Published: MDPI AG 2019-07-01
Series:Inorganics
Subjects:
copper complex
imidazole
cyano
alcoholysis
structural analysis
DFT
QTAIM (Quantum Theory of Atoms in Molecules)
Online Access:https://www.mdpi.com/2304-6740/7/7/87

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https://www.mdpi.com/2304-6740/7/7/87

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