Questions on selectivity of homo- and crossaldol condensation of lower aldehydes at presence of different salts of amines.
Reactions of homo- and crossaldol condensation of formaldehyde and acetaldehyde were studied at presence of primary, secondary and tertiary amine salt of linear structure in N,N-dimethylacetamide, water and toluene. It was found that in all solvents conversion of reagent is increased with increase o...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | Russian |
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MIREA - Russian Technological University
2008-08-01
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| Series: | Тонкие химические технологии |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/1509 |
| Summary: | Reactions of homo- and crossaldol condensation of formaldehyde and acetaldehyde were studied at presence of primary, secondary and tertiary amine salt of linear structure in N,N-dimethylacetamide, water and toluene. It was found that in all solvents conversion of reagent is increased with increase of bacity of amine, but selectivity on cross-reaction became lower because of formation side products of acetaldehyde homo-condensation. The conversion of acetaldehyde is also increased with increase of solvent polarity. |
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| ISSN: | 2410-6593 2686-7575 |